Question

$$\left[ X \right] + {H_2}S{O_4} \to \left[ Y \right]$$     a colourless gas with irritating smell, $$\left[ Y \right] + {K_2}C{r_2}{O_7} + {H_2}S{O_4} \to $$      green solution. $$[X]$$  and $$[Y]$$  is :

A. $$SO_3^{2 - },S{O_2}$$  
B. $$C{l^ - },HCl$$
C. $${S^{2 - }},{H_2}S$$
D. $$CO_3^{2 - },C{O_2}$$
Answer :   $$SO_3^{2 - },S{O_2}$$
Solution :
$$S{O_2}$$  and $${H_2}S$$  both being reducing agents, can turn acidified dichromate solution green. $$S{O_2}$$  can be obtained by the action of acid upon sulphite while $${H_2}S$$  is evolved by the action of acid upon sulphide. However, $$S{O_2}$$  has a burning sulphur smell which is irritating. $${H_2}S$$  has rotten egg like smell.

Releted MCQ Question on
Inorganic Chemistry >> Qualitative Analysis

Releted Question 1

The ion that cannot be precipitated by both $$HCl\,{\text{and}}\,{H_2}S$$    is

A. $$P{b^{2 + }}$$
B. $$C{u^ + }$$
C. $$A{g^ + }$$
D. $$S{n^{2 + }}$$
Releted Question 2

Which one among the following pairs of ions cannot be separated by $${H_2}S$$  in dilute hydrochloric acid?

A. $$B{i^{3 + }},S{n^{4 + }}$$
B. $$A{l^{3 + }},H{g^{2 + }}$$
C. $$Z{n^{2 + }},C{u^{2 + }}$$
D. $$N{i^{2 + }},C{u^{2 + }}$$
Releted Question 3

An aqueous solution contains $$H{g^{2 + }},Hg_2^{2 + },P{b^{2 + }}\,{\text{and}}\,C{d^{2 + }}.$$
The addition of $$HCl\left( {6N} \right)$$   will precipitate:

A. $$H{g_2}C{l_2}\,{\text{only}}$$
B. $$PbC{l_2}\,{\text{only}}$$
C. $$PbC{l_2}\,{\text{and}}\,H{g_2}C{l_2}$$
D. $$PbC{l_2}\,{\text{and}}\,HgC{l_2}$$
Releted Question 4

Identify the correct order of solubility of $$N{a_2}S,\,CuS\,{\text{and}}\,ZnS$$     in aqueous medium

A. $$CuS > ZnS > N{a_2}S$$
B. $$ZnS > N{a_2}S > CuS$$
C. $$N{a_2}S > CuS > ZnS$$
D. $$N{a_2}S > ZnS > CuS$$

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