which one of the following esters cannot undergo claisen

Which one of the following esters cannot undergo Claisen self-condensation ?

A. $$C{H_3}C{H_2}C{H_2}C{H_2}COO{C_2}{H_5}$$

B. $${C_6}{H_5}COO{C_2}{H_5}$$

C. $${C_6}{H_5}C{H_2}COO{C_2}{H_5}$$

D. $${C_6}{H_{11}}C{H_2}COO{C_2}{H_5}$$

Answer : $${C_6}{H_5}COO{C_2}{H_5}$$

Solution :
The ester which contains $$\alpha $$ - hydrogen atom undergoes Claisen-self condensation :
Carboxylic Acid mcq solution image

Releted MCQ Question on
Organic Chemistry >> Carboxylic Acid

Releted Question 1

When acetaldehyde is heated with Fehling’s solution it gives a precipitate of

A. $$Cu$$

B. $$CuO$$

C. $$C{u_2}O$$

D. $$Cu + C{u_2}O + CuO$$

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Releted Question 2

In the Cannizzaro reaction given below,
\[2PhCHO\xrightarrow{^{-}OH}PhC{{H}_{2}}OH+PhCO_{2}^{-},\]
the slowest step is

A. the attack of $$^ - OH$$ at the carbonyl group,

B. the transfer of hydride to the carbonyl group,

C. the abstraction of proton from the carboxylic acid,

D. the deprotonation of $$PhC{H_2}OH.$$

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Releted Question 3

When propionic acid is treated with aqueous sodium bicarbonate, $$C{O_2}$$ is liberated. The $$'C'$$ of $$C{O_2}$$ comes from

A. methyl group

B. carboxylic acid group

C. methylene group

D. bicarbonate

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Releted Question 4

Benzoyl chloride is prepared from benzoic acid by

A. $$C{l_2},hv$$

B. $$S{O_2}C{l_2}$$

C. $$SOC{l_2}$$

D. $$C{l_2},{H_2}O$$

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Which one of the following esters cannot undergo Claisen self-condensation ?

Releted MCQ Question on
Organic Chemistry >> Carboxylic Acid

When acetaldehyde is heated with Fehling’s solution it gives a precipitate of

In the Cannizzaro reaction given below,
\[2PhCHO\xrightarrow{^{-}OH}PhC{{H}_{2}}OH+PhCO_{2}^{-},\]
the slowest step is

When propionic acid is treated with aqueous sodium bicarbonate, $$C{O_2}$$ is liberated. The $$'C'$$ of $$C{O_2}$$ comes from

Benzoyl chloride is prepared from benzoic acid by

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Carboxylic Acid

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Which one of the following esters cannot undergo Claisen self-condensation ?

Releted MCQ Question on Organic Chemistry >> Carboxylic Acid

When acetaldehyde is heated with Fehling’s solution it gives a precipitate of

In the Cannizzaro reaction given below, \[2PhCHO\xrightarrow{^{-}OH}PhC{{H}_{2}}OH+PhCO_{2}^{-},\] the slowest step is

When propionic acid is treated with aqueous sodium bicarbonate, $$C{O_2}$$ is liberated. The $$'C'$$ of $$C{O_2}$$ comes from

Benzoyl chloride is prepared from benzoic acid by

Practice More Releted MCQ Question on Carboxylic Acid

Practice More MCQ Question on Chemistry Section

Releted MCQ Question on
Organic Chemistry >> Carboxylic Acid

In the Cannizzaro reaction given below,
\[2PhCHO\xrightarrow{^{-}OH}PhC{{H}_{2}}OH+PhCO_{2}^{-},\]
the slowest step is

Practice More Releted MCQ Question on
Carboxylic Acid