Question

Which of the following statements is correct about the given Daniell cell?
Electrochemistry mcq question image

A. This cell converts the electrical energy liberated during the redox reaction to chemical energy.
B. This cell has an electrical potential greater than $$1.1\,V$$  when concentration of $$Z{n^{2 + }}$$  and $$C{u^{2 + }}$$  ions is unity $$\left( {1\,mol\,d{m^{ - 3}}} \right).$$
C. In this cell, copper is acting as cathode and zinc is acting as anode.  
D. Redox reaction occurring in this cell is $$C{u_{\left( s \right)}} + Zn_{\left( {aq} \right)}^{2 + } \to Cu_{\left( {aq} \right)}^{2 + } + Z{n_{\left( s \right)}}$$
Answer :   In this cell, copper is acting as cathode and zinc is acting as anode.

Releted MCQ Question on
Physical Chemistry >> Electrochemistry

Releted Question 1

The standard reduction potentials at $$298 K$$  for the following half reactions are given against each
$$\eqalign{ & Z{n^{2 + }}\left( {aq} \right) + 2e \rightleftharpoons Zn\left( s \right)\,\,\,\,\,\,\,\,\, - 0.762 \cr & C{r^{3 + }}\left( {aq} \right) + 2e \rightleftharpoons Cr\left( s \right)\,\,\,\,\,\,\,\,\, - 0.740 \cr & 2{H^ + }\left( {aq} \right) + 2e \rightleftharpoons {H_2}\left( g \right)\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,0.000 \cr & F{e^{3 + }}\left( {aq} \right) + 2e \rightleftharpoons F{e^{2 + }}\left( {aq} \right)\,\,\,\,\,\,\,\,0.770 \cr} $$
which is the strongest reducing agent ?

A. $$Zn\left( s \right)$$
B. $$Cr\left( s \right)$$
C. $${H_2}\left( g \right)$$
D. $$F{e^{2 + }}\left( {aq} \right)$$
Releted Question 2

Faraday’s laws of electrolysis are related to the

A. atomic number of the reactants.
B. atomic number of the anion.
C. equivalent weight of the electrolyte.
D. speed of the cation.
Releted Question 3

A solution containing one mole per litre of each $$Cu{\left( {N{O_3}} \right)_2};AgN{O_3};H{g_2}{\left( {N{O_3}} \right)_2};$$       is being electrolysed by using inert electrodes. The values of standard electrode potentials in volts (reduction potentials) are :
$$\eqalign{ & Ag/A{g^ + } = + 0.80,\,\,2Hg/H{g_2}^{ + + } = + 0.79 \cr & Cu/C{u^{ + + }} = + 0.34,\,Mg/M{g^{ + + }} = - 2.37 \cr} $$
With increasing voltage, the sequence of deposition of metals on the cathode will be :

A. $$Ag,Hg,Cu,Mg$$
B. $$Mg,Cu,Hg,Ag$$
C. $$Ag,Hg,Cu$$
D. $$Cu,Hg,Ag$$
Releted Question 4

The electric charge for electrode deposition of one gram equivalent of a substance is :

A. one ampere per second.
B. 96,500 coloumbs per second.
C. one ampere for one hour.
D. charge on one mole of electrons.

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