Question

Which of the following reaction can produce \[R-CO-Ar?\]

A. \[ArCOCl+H-Ar\xrightarrow{AlC{{l}_{3}}}\]  
B. \[RCOCl+ArMgX\to \]
C. \[ArCOCl+RMgX\to \]
D. \[RCOCl+H-Ar\xrightarrow{AlC{{l}_{3}}}\]
Answer :   \[ArCOCl+H-Ar\xrightarrow{AlC{{l}_{3}}}\]
Solution :
$$ArCOR$$   can be prepared by the combination of $$ArH + RCOCl$$    and not by $$ArCOCl + RMgX$$     because here the $$ArCOR$$   formed will further react with $$RMgX$$   to form \[{{3}^{\circ }}\] alcohol, \[ArC\left( OH \right){{R}_{2}}\]    as the final products.

Releted MCQ Question on
Organic Chemistry >> Aldehyde and Ketone

Releted Question 1

The reagent with which both acetaldehyde and acetone react easily is

A. Fehling’s reagent
B. Grignard reagent
C. Schiff’s reagent
D. Tollen’s reagent
View Answer
Releted Question 2

The Cannizzaro reaction is not given by

A. trimethylacetaldehye
B. acetaldehyde
C. benzaldehyde
D. formaldehyde
View Answer
Releted Question 3

The compound that will not give iodoform on treatment with alkali and iodine is :

A. acetone
B. ethanol
C. diethyl ketone
D. isopropyl alcohol
View Answer
Releted Question 4

Polarisation of electrons in acrolein may be written as

A. $$\mathop {C{H_2}}\limits^{{\delta ^ - }} = CH - \mathop {CH}\limits^{{\delta ^ + }} = O$$
B. $$\mathop {C{H_2}}\limits^{{\delta ^ - }} = CH - CH = \mathop O\limits^{{\delta ^ + }} $$
C. $$\mathop {C{H_2}}\limits^{{\delta ^ - }} = \mathop {CH}\limits^{{\delta ^ + }} - CH = O$$
D. $$\mathop {C{H_2}}\limits^{{\delta ^ + }} = CH - CH = \mathop O\limits^{{\delta ^ - }} $$
View Answer

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Aldehyde and Ketone

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Physical ChemistrySome Basic Concepts in ChemistryStoichiometryStates of Matter Solid, Liquid and GasAtomic StructureChemical ThermodynamicsSolutionsSolid StateSurface ChemistryChemical EquilibriumIonic EquilibriumChemical KineticsRedox ReactionElectrochemistryNuclear Chemistry
Inorganic ChemistryChemical Bonding and Molecular StructureOres and MetallurgyClassification of Elements and Periodicity in PropertiesHydrogenS - Block ElementsP - Block ElementsD and F Block ElementsCo - ordination CompoundsQualitative AnalysisPreparation and Properties of CompoundsEnvironmental Chemistry
Organic ChemistryGeneral Organic ChemistryIsomerismPurification and Characterisation of Organic CompoundsHydrocarbons (Alkane, Alkene and Alkyne)Aromatic hydrocarbonElectrophilic Aromatic Substitution (Haloalkanes and Haloarenes)Alkyl and Aryl HalideReactions on BenzeneAlcohol, Phenol and EtherAldehyde and KetoneCarboxylic AcidOrganic Compounds Containing NitrogenName ReactionsPolymersBiomoleculesChemistry in Everyday LifePractical Organic Chemistry