Question

Which of the following products are not correctly matched in the given reactions?

A. \[{{C}_{2}}{{H}_{5}}OC{{H}_{3}}+HBr\xrightarrow{373\,K}\]      \[{{C}_{2}}{{H}_{5}}OH+C{{H}_{3}}Br\]
B. $${C_2}{H_5}O{C_2}{H_5} + \mathop {2HI}\limits_{{\text{Excess}}} \to $$      $${C_2}{H_5}I + {C_2}{H_5}OH$$  
C. \[{{C}_{2}}{{H}_{5}}O{{C}_{2}}{{H}_{5}}+HCl\xrightarrow{\text{Cold}}\]      \[\left[ {{\left( {{C}_{2}}{{H}_{5}} \right)}_{2}}{{O}^{+}}H \right]C{{l}^{-}}\]
D. \[{{\left( C{{H}_{3}} \right)}_{3}}CO{{C}_{2}}{{H}_{5}}\xrightarrow{\text{HI}}\]     \[{{\left( C{{H}_{3}} \right)}_{3}}CI+{{C}_{2}}{{H}_{5}}OH\]
Answer :   $${C_2}{H_5}O{C_2}{H_5} + \mathop {2HI}\limits_{{\text{Excess}}} \to $$      $${C_2}{H_5}I + {C_2}{H_5}OH$$
Solution :
$${C_2}{H_5} - O - {C_2}{H_5} + \mathop {2HI}\limits_{\left( {{\text{excess}}} \right)} \to $$       $$2{C_2}{H_5}I + {H_2}O$$

Releted MCQ Question on
Organic Chemistry >> Alcohol, Phenol and Ether

Releted Question 1

Ethyl alcohol is heated with conc $${H_2}S{O_4}$$  the product formed is

A. \[{{H}_{3}}C\underset{\begin{smallmatrix} \parallel \\ O \end{smallmatrix}}{\mathop{-C-}}\,O{{C}_{2}}{{H}_{5}}\]
B. $${C_2}{H_6}$$
C. $${C_2}{H_4}$$
D. $${C_2}{H_2}$$
Releted Question 2

The compound which reacts fastest with Lucas reagent at room temperature is

A. $${\text{butan - 1 - ol}}$$
B. $${\text{butan - 2 - ol}}$$
C. $${\text{2 - methylpropan - 1 - ol}}$$
D. $${\text{2 - methylpropan - 2 - ol}}$$
Releted Question 3

A compound that gives a positive iodoform test is

A. 1 - pentanol
B. 2 - pentanone
C. 3 - pentanone
D. pentanal
Releted Question 4

Diethyl ether on heating with conc. $$HI$$  gives two moles of $$H$$

A. ethanol
B. iodoform
C. ethyl iodide
D. methyl iodide

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Alcohol, Phenol and Ether


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