Question

When alkaline earth metals dissolve in ammonia, they form coloured solution like alkali metals. Which of the following observations regarding the reaction are correct?
(i) Dilute solutions are bright blue in colour due to solvated electrons.
(ii) These solutions decompose to form amides and hydrogen.
(iii) From this solution the ammoniates $${\left[ {M{{\left( {N{H_3}} \right)}_6}} \right]^{2 + }}$$   can be recovered by evaporation.

A. Only (i) and (ii)
B. (i), (ii) and (iii)  
C. Only (ii) and (iii)
D. Only (i)
Answer :   (i), (ii) and (iii)
Solution :
$$\eqalign{ & {\text{All the observations are correct}}{\text{.}} \cr & M \to {M^{2 + }} + 2{e^ - } \cr & 2N{H_3} + 2{e^ - } \to 2NH_2^ - + {H_2} \cr} $$
$${M^{2 + }} + 2NH_2^ - \to M{\left( {N{H_2}} \right)_2}$$      \[\xrightarrow{\text{evaporation}}{{\left[ M{{\left( N{{H}_{3}} \right)}_{6}} \right]}^{2+}}\]
$${\left[ {M{{\left( {N{H_3}} \right)}_6}} \right]^{2 + }} \to M{\left( {N{H_2}} \right)_2}$$       $$ + 4N{H_3} + {H_2}$$

Releted MCQ Question on
Inorganic Chemistry >> S - Block Elements

Releted Question 1

A substance absorbs $$C{O_2}$$  and voilently reacts with water. The substance is

A. $$CaC{O_3}$$
B. $$CaO$$
C. $${H_2}S{O_4}$$
D. $$ZnO$$
Releted Question 2

Calcium is obtained by

A. electrolysis of molten $$CaC{l_2}.$$
B. electrolysis of solution of $$CaC{l_2}$$  in water.
C. Reduction of $$CaC{l_2}$$  with carbon.
D. roasting of limestone.
Releted Question 3

A solution of sodium metal in liquid ammonia is strongly reducing due to the presence of

A. sodium atoms
B. sodium hydride
C. sodium amide
D. solvated electrons
Releted Question 4

The hydration energy of $$M{g^{ + + }}$$  is larger than that of :

A. $$A{l^{3 + }}$$
B. $$N{a^ + }$$
C. $$B{e^{ + + }}$$
D. $$M{g^{3 + }}$$

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S - Block Elements


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