Question

The species which by definition has zero standard molar enthalpy of formation at $$298\,K$$  is

A. $$B{r_2}\left( g \right)$$
B. $$C{l_2}\left( g \right)$$  
C. $${H_2}O\left( g \right)$$
D. $$C{H_4}\left( g \right)$$
Answer :   $$C{l_2}\left( g \right)$$
Solution :
The species in its elemental form has zero standard molar enthalpy of formation at $$298\,K.$$   At $$298\,K,C{l_2}$$   is gas while $$B{r_2}$$  is liquid.

Releted MCQ Question on
Physical Chemistry >> Chemical Thermodynamics

Releted Question 1

The difference between heats of reaction at constant pressure and constant volume for the reaction : $$2{C_6}{H_6}\left( l \right) + 15{O_{2\left( g \right)}} \to $$     $$12C{O_2}\left( g \right) + 6{H_2}O\left( l \right)$$     at $${25^ \circ }C$$  in $$kJ$$ is

A. $$-$$ 7.43
B. $$+$$ 3.72
C. $$-$$ 3.72
D. $$+$$ 7.43
Releted Question 2

For which change $$\Delta H \ne \Delta E\,:$$

A. $${H_{2\left( g \right)}} + {I_{2\left( g \right)}} \to 2HI\left( g \right)$$
B. $$HC{\text{l}} + NaOH \to NaC{\text{l}}$$
C. $${C_{\left( s \right)}} + {O_{{2_{\left( g \right)}}}} \to C{o_{{2_{\left( g \right)}}}}$$
D. $${N_2}\left( g \right) + 3{H_2}\left( g \right) \to 2N{H_3}\left( g \right)$$
Releted Question 3

$${\text{The}}\,\Delta H_f^0\,{\text{for}}\,C{O_2}\left( g \right),\,CO\left( g \right)\,$$     and $${H_2}O\left( g \right)$$   are $$-393.5,$$  $$-110.5$$  and $$ - 241.8\,kJ\,mo{l^{ - 1}}$$    respectively. The standard enthalpy change ( in $$kJ$$ ) for the reaction $$C{O_2}\left( g \right) + {H_2}\left( g \right) \to CO\left( g \right) + {H_2}O\left( g \right)\,{\text{is}}$$

A. 524.1
B. 41.2
C. -262.5
D. -41.2
Releted Question 4

In thermodynamics, a process is called reversible when

A. surroundings and system change into each other.
B. there is no boundary between system and surroundings.
C. the surroundings are always in equilibrium with the system.
D. the system changes into the surroundings spontaneously.

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Chemical Thermodynamics


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