Question

The reason for the stability of $$G{d^{3 + }}\,ion$$   is

A. $$4f$$  subshell - half filled.  
B. $$4f$$  subshell - completely filled.
C. Possesses the general electronic configuration of noble gases.
D. $$4f$$  subshell empty.
Answer :   $$4f$$  subshell - half filled.
Solution :
$$\eqalign{ & Gd\left( {Z = 64} \right) \Rightarrow 4{f^7}5{d^1}6{s^2} \cr & G{d^{3 + }} = 4{f^7} \cr} $$
$$G{d^{3 + }}$$  is stable due to the presence of exactly half-filled $$4f$$ - subshell.

Releted MCQ Question on
Inorganic Chemistry >> D and F Block Elements

Releted Question 1

When same amount of zinc is treated separately with excess of sulphuric acid and excess of sodium hydroxide, the ratio of volume of hydrogen evolved is

A. $$1:1$$
B. $$1:2$$
C. $$2:1$$
D. $$9:4$$
Releted Question 2

Which of the following is the weakest base

A. $$NaOH$$
B. $$Ca{\left( {OH} \right)_2}$$
C. $$KOH$$
D. $$Zn{\left( {OH} \right)_2}$$
Releted Question 3

One of the constituent of German silver is

A. $$Ag$$
B. $$Cu$$
C. $$Mg$$
D. $$Al$$
Releted Question 4

Which of the following dissolve in hot conc.$$NaOH$$  solution

A. $$Fe$$
B. $$Zn$$
C. $$Cu$$
D. $$Ag$$

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D and F Block Elements


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