Question

The organic product formed in the reaction
\[{{C}_{6}}{{H}_{5}}COOH\xrightarrow[II\,{{H}_{3}}{{O}^{+}}]{I\,LiAl{{H}_{4}}}\]

A. \[{{C}_{6}}{{H}_{5}}C{{H}_{2}}OH\]  
B. \[{{C}_{6}}{{H}_{5}}COOH\,\And C{{H}_{4}}\]
C. \[{{C}_{6}}{{H}_{5}}C{{H}_{3}}\,\And \,C{{H}_{3}}OH\]
D. \[{{C}_{6}}{{H}_{5}}C{{H}_{3}}\,\And \,C{{H}_{4}}\]
Answer :   \[{{C}_{6}}{{H}_{5}}C{{H}_{2}}OH\]
Solution :
TIPS/FORMULAE :
$$LiAl{H_4}$$  is a reducing agent, it reduces $$ - COOH$$   group to $$ - C{H_2}OH$$   group.
\[{{C}_{6}}{{H}_{5}}COOH\xrightarrow{LiAl{{H}_{4}}}{{C}_{6}}{{H}_{5}}C{{H}_{2}}OH\]

Releted MCQ Question on
Organic Chemistry >> Aldehyde and Ketone

Releted Question 1

The reagent with which both acetaldehyde and acetone react easily is

A. Fehling’s reagent
B. Grignard reagent
C. Schiff’s reagent
D. Tollen’s reagent
Releted Question 2

The Cannizzaro reaction is not given by

A. trimethylacetaldehye
B. acetaldehyde
C. benzaldehyde
D. formaldehyde
Releted Question 3

The compound that will not give iodoform on treatment with alkali and iodine is :

A. acetone
B. ethanol
C. diethyl ketone
D. isopropyl alcohol
Releted Question 4

Polarisation of electrons in acrolein may be written as

A. $$\mathop {C{H_2}}\limits^{{\delta ^ - }} = CH - \mathop {CH}\limits^{{\delta ^ + }} = O$$
B. $$\mathop {C{H_2}}\limits^{{\delta ^ - }} = CH - CH = \mathop O\limits^{{\delta ^ + }} $$
C. $$\mathop {C{H_2}}\limits^{{\delta ^ - }} = \mathop {CH}\limits^{{\delta ^ + }} - CH = O$$
D. $$\mathop {C{H_2}}\limits^{{\delta ^ + }} = CH - CH = \mathop O\limits^{{\delta ^ - }} $$

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Aldehyde and Ketone


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