Solution :
The natural numbers are 1, 2, 3, 4.

Clearly, in one diagonal we have to place 1, 4 and in the other 2, 3.
The number of ways in (i) $$ = 2!\, \times 2! = 4.$$
The number of ways in (ii) $$ = 2!\, \times 2! = 4.$$
∴ the total number of ways = 8.