Question

The Lassaigne’s extract is boiled with $$dil.\,HN{O_3}$$   before testing for halogens because

A. silver halides are soluble in $$HN{O_3}$$
B. $$N{a_2}S$$  and $$NaCN$$  are decomposed by $$HN{O_3}$$  
C. $$A{g_2}S$$  is soluble in $$HN{O_3}$$
D. $$AgCN$$  is soluble in $$HN{O_3}$$
Answer :   $$N{a_2}S$$  and $$NaCN$$  are decomposed by $$HN{O_3}$$
Solution :
$$N{a_2}S$$  and $$NaCN,$$  formed during fusion with metallic sodium, must be removed before adding $$AgN{O_3},$$  otherwise black $$ppt.$$  due to $$N{a_2}S$$  or white precipitate due to $$AgCN$$  will be formed and thus white precipitate of $$AgCl$$  will not be identified easily.
\[\begin{align} & N{{a}_{2}}S+2AgN{{O}_{3}}\to 2NaN{{O}_{3}}+\underset{\text{Black}}{\mathop{A{{g}_{2}}S\downarrow }}\, \\ & NaCN+AgN{{O}_{3}}\to NaN{{O}_{3}}+\underset{\text{White}}{\mathop{AgCN\downarrow }}\, \\ & NaCl+AgN{{O}_{3}}\to NaN{{O}_{3}}+\underset{\text{White}}{\mathop{AgCl\downarrow }}\, \\ & N{{a}_{2}}S+2HN{{O}_{3}}\xrightarrow{\text{boil}}2NaN{{O}_{3}}+{{H}_{2}}S\uparrow \\ & NaCN+HN{{O}_{3}}\xrightarrow{\text{boil}}NaN{{O}_{3}}+HCN\uparrow \\ \end{align}\]

Releted MCQ Question on
Inorganic Chemistry >> Preparation and Properties of Compounds

Releted Question 1

The compound formed in the positive test for nitrogen with the Lassaigne solution of an organic compound is

A. $$F{e_4}{\left[ {Fe{{\left( {CN} \right)}_6}} \right]_3}$$
B. $$N{a_3}\left[ {Fe{{\left( {CN} \right)}_6}} \right]$$
C. $$Fe{\left( {CN} \right)_3}$$
D. $$N{a_4}\left[ {Fe{{\left( {CN} \right)}_5}NOS} \right]$$
Releted Question 2

Which of the following , upon treatment with tert-BuONa followed by addition of bromine water, fails to decolourize the colour of bromine?

A. Preparation and Properties of Compounds mcq option image
B. Preparation and Properties of Compounds mcq option image
C. Preparation and Properties of Compounds mcq option image
D. Preparation and Properties of Compounds mcq option image
Releted Question 3

Which of the following compounds will be suitable for Kjeldahl’s method for nitrogen estimation?

A. Preparation and Properties of Compounds mcq option image
B. Preparation and Properties of Compounds mcq option image
C. Preparation and Properties of Compounds mcq option image
D. Preparation and Properties of Compounds mcq option image
Releted Question 4

An alkali is titrated against an acid with methyl orange as indicator, which of the following in a correct combination?
Preparation and Properties of Compounds mcq question image

A. (a)
B. (b)
C. (c)
D. (d)

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