Question

The electrons, identified by quantum numbers $$n$$ and $$l,$$
(i) $$n = 4,\,l = 1,$$   (ii) $$n = 4,\,l = 0,$$   (iii) $$n = 3,\,l = 2,$$   and (iv) $$n = 3,\,l = 1,$$   can be placed in order of increasing energy, from the lowest to highest, as

A. (iv) < (ii) < (iii) < (i)  
B. (ii) < (iv) < (i) < (iii)
C. (i) < (iii) < (ii) < (iv)
D. (iii) < (i) < (iv) < (ii)
Answer :   (iv) < (ii) < (iii) < (i)
Solution :
TIPS/Formulae : The two guiding rules to arrange the various orbitals in the increasing energy are:
(i) Energy of an orbital increases with increase in the value of $$n + l.$$
(ii) Of orbitals having the same value of $$n + l,$$ the orbital with lower value of n has lower energy.
Thus for the given orbitals, we have
$$\eqalign{ & ({\text{i}})\,\,n + l = 4 + 1 = 5 \cr & {\text{(ii)}}\,n + l = 4 + 0 = 4 \cr & {\text{(iii)}}\,n + l = 3 + 2 = 5 \cr & {\text{(iv)}}\,n + l = 3 + 1 = 4 \cr} $$
Hence, the order of increasing energy is (iv) < (ii) < (iii) < (i)

Releted MCQ Question on
Physical Chemistry >> Atomic Structure

Releted Question 1

The number of neutrons in dipositive zinc ion with mass number 70 is

A. 34
B. 36
C. 38
D. 40
Releted Question 2

Rutherford’s experiment on scattering of $$a$$ -particles showed for the first time that the atom has

A. electrons
B. protons
C. nucleus
D. neutrons
Releted Question 3

Any $$p-$$orbital can accommodate upto

A. four electrons
B. six electrons
C. two electrons with parallel spins
D. two electrons with opposite spins
Releted Question 4

The principal quantum number of an atom is related to the

A. size of the orbital
B. spin angular momentum
C. orbital angular momentum
D. orientation of the orbital in space

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Atomic Structure


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