Question

The compound obtained by heating a mixture of primary amine and chloroform with ethanolic potassium hydroxide $$(KOH)$$  is

A. an alkyl isocyanide  
B. an alkyl halide
C. an amide
D. an amide and nitro compound
Answer :   an alkyl isocyanide
Solution :
$$RN{H_2} + CHC{l_3} + 3KOH\left( {{\text{alc}}{\text{.}}} \right) \to \mathop {RNC}\limits_{{\text{Alkyl isocyanide}}} + 3KCl + 3{H_2}O$$
This reaction is known as carbylamine test. ( only $${1^ \circ }$$ amine gives this reaction )

Releted MCQ Question on
Organic Chemistry >> Organic Compounds Containing Nitrogen

Releted Question 1

The compound which on reaction with aqueous nitrous acid at low temperature produces an oily nitrosamine is

A. methylamine
B. ethylamine
C. diethylamine
D. triethylamine
Releted Question 2

Acetamide is treated separately with the following reagents. Which one of these would give methylamine?

A. $$PC{l_5}$$
B. $$NaOH + B{r_2}$$
C. soda lime
D. hot conc. $${H_2}S{O_4}$$
Releted Question 3

Carbylamine test is performed in alcoholic \[KOH\]  by heating a mixture of :

A. chloroform and silver powder
B. trihalogenatedmethane and a primary amine
C. an alkyl halide anda primary amine
D. an alkyl cyanide and a primary amine
Releted Question 4

The compound that is most reactive towards electrophilic nitration is :

A. toluene
B. benzene
C. benzoic acid
D. nitrobenzene

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Organic Compounds Containing Nitrogen


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