Question

The amount of energy when million atoms of iodine are completely converted into $${I^ - }$$ ions in the vapour state according to the equation, $${I_{\left( g \right)}} + {e^ - } \to I_{\left( g \right)}^ - $$    is $$4.9 \times {10^{ - 13}}\,J.$$   What would be the electron gain enthalpy of iodine in terms of $$kJ\,mo{l^{ - 1}}$$  and $$eV$$  per atom?

A. 295, 3.06
B. - 295, - 3.06  
C. 439, 5.09
D. - 356, - 7.08
Answer :   - 295, - 3.06
Solution :
The electron gain enthalpy of iodine is equal to the energy released when 1 mole of iodine atoms in vapour state is converted into $${I^ - }$$ ions
$$\eqalign{ & {\Delta _{eg}}H = \frac{{4.9 \times {{10}^{ - 13}} \times 6.023 \times {{10}^{23}}}}{{{{10}^6}}} \cr & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\, = 29.5 \times {10^4}\,J\,mo{l^{ - 1}} \cr & \,\,\,\,\,\,\,\,\,\,\,\,\,\,\, = 295\,kJ\,mo{l^{ - 1}} \cr} $$
Thus, electron gain enthalpy of iodine $$ = - 295\,kJ\,mo{l^{ - 1}}$$
We know that 1 $$eV$$  per atom $$ = 96.49\,kJ\,mo{l^{ - 1}}$$
∴ Electron gain enthalpy of iodine in $$eV$$  per atom $$ = - \frac{{295}}{{96.49}} = - 3.06\,eV$$     per atom

Releted MCQ Question on
Inorganic Chemistry >> Classification of Elements and Periodicity in Properties

Releted Question 1

The correct order of second ionisation potential of carbon, nitrogen, oxygen and fluorine is

A. $$C > N > O > F$$
B. $$O > N > F > C$$
C. $$O > F > N > C$$
D. $$F > O > N > C$$
Releted Question 2

The element with the highest first ionization potential is

A. boron
B. carbon
C. nitrogen
D. oxygen
Releted Question 3

The first ionisation potential in electron volts of nitrogen and oxygen atoms are respectively given by

A. $$14.6,13.6\,$$
B. $$13.6,14.6$$
C. $$13.6,13.6$$
D. $$14.6,14.6$$
Releted Question 4

Atomic radii of fluorine and neon in $$\mathop {\text{A}}\limits^ \circ $$ngstorm units are respectively given by

A. $$0.72,1.60$$
B. $$1.60,1.60\,$$
C. $$0.72,0.72\,\,$$
D. None of these values

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Classification of Elements and Periodicity in Properties


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