Question

Stability of the species $$L{i_2},Li_2^ - $$  and $$Li_2^ + $$  increases in the order of:

A. $$L{i_2} < Li_2^ + < Li_2^ - $$
B. $$Li_2^ - < Li_2^ + < L{i_2}$$  
C. $$L{i_2} < Li_2^ - < Li_2^ + $$
D. $$Li_2^ - < L{i_2} < Li_2^ + $$
Answer :   $$Li_2^ - < Li_2^ + < L{i_2}$$
Solution :
$$L{i_2} = \sigma 1{s^2}{\sigma ^*}1{s^2}\sigma 2{s^2},$$     ∴ Bond order $$\, = \frac{1}{2}\left( {4 - 2} \right) = 1$$
$$Li_2^ + = \sigma 1{s^2}{\sigma ^*}1{s^2}\sigma 2{s^1},$$     $$B.O.$$  $$ = \frac{1}{2}\left( {3 - 2} \right) = 0.5$$
$$Li_2^ - = \sigma 1{s^2}{\sigma ^*}1{s^2}\sigma 2{s^2}{\sigma ^*}2{s^1},$$      $$B.O.$$  $$ = \frac{1}{2}\left( {4 - 3} \right) = 0.5$$
The bond order of $$Li_2^ + $$ and $$Li_2^ - $$ is same but $$Li_2^ + $$  is more stable than $$Li_2^ - $$  because $$Li_2^ + $$  is smaller in size and has $$2$$  electrons in Anti bonding orbital whereas $$Li_2^ - $$ has $$3$$ electrons in Anti bonding orbital. hence $$Li_2^ + $$  is more stable than $$Li_2^ - $$

Releted MCQ Question on
Inorganic Chemistry >> Chemical Bonding and Molecular Structure

Releted Question 1

The compound which contains both ionic and covalent bonds is

A. $$C{H_4}$$
B. $${H_2}$$
C. $$KCN$$
D. $$KCl$$
Releted Question 2

The octet rule is not valid for the molecule

A. $$C{O_2}$$
B. $${H_2}O$$
C. $${O_2}$$
D. $$CO$$
Releted Question 3

Element $$X$$ is strongly electropositive and element $$Y$$ is strongly electronegative. Both are univalent. The compound formed would be

A. $${X^ + }{Y^ - }$$
B. $${X^ - }{Y^{ + \,}}$$
C. $$X - Y$$
D. $$X \to Y$$
Releted Question 4

Which of the following compounds are covalent?

A. $${H_2}$$
B. $$CaO$$
C. $$KCl$$
D. $$N{a_2}S$$

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Chemical Bonding and Molecular Structure


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