111.
The ionisation energy of the electron in the hydrogen atom in its ground state is $$13.6\,eV.$$ The atoms are excited to higher energy levels to emit radiations of 6 wavelengths. Maximum wavelength of emitted radiation corresponds to the transition between
Number of spectral lines
$$\eqalign{
& N = \frac{{n\left( {n - 1} \right)}}{2} \Rightarrow \frac{{n\left( {n - 1} \right)}}{2} = 6 \cr
& {\text{or}}\,\,{n^2} - n - 12 = 0 \cr
& {\text{or}}\,\,\left( {n - 4} \right)\left( {n + 3} \right) = 0 \cr
& {\text{or}}\,\,n = 4 \cr} $$
Now as the first line of the series has the maximum wavelength, therefore electron jumps from the fourth orbit to the third orbit.
112.
The transition from the state $$n = 4$$ to $$n = 3$$ in a hydrogen-like atom results in ultraviolet radiation. Infrared radiation will be obtained in the transition
For 2 to 1, 3 to 2 and 4 to 2 we get energy that $$n =4$$ to $$n = 3,$$
I.R. radiation has less energy than U. V. radiation.
113.
Suppose an electron is attracted towards the origin by a force $$\frac{k}{r}$$ where $$k$$ is a constant and $$r$$ is the distance of the electron from the origin. By applying Bohr model to this system, the radius of the nth orbital of the electron is found to be $$'{r_n}'$$ and the kinetic energy of the electron to be $$'{K_n}'.$$ Then which of the following is true
A
$${K_n}$$ independent of $$n,{r_n} \propto n$$
B
$${K_n} \propto \frac{1}{n},{r_n} \propto n$$
C
$${K_n} \propto \frac{1}{n},{r_n} \propto {n^2}$$
D
$${K_n} \propto \frac{1}{{{n^2}}},{r_n} \propto {n^2}$$
Answer :
$${K_n}$$ independent of $$n,{r_n} \propto n$$
114.
If the wavelength of the first line of the Balmer series in the hydrogen spectrum is $$\lambda ,$$ then the wavelength of the first line of the Lyman series is
For first line of Balmer series
$$\eqalign{
& \frac{1}{\lambda } = R\left( {\frac{1}{4} - \frac{1}{9}} \right) \cr
& \Rightarrow R = \frac{{36}}{{5\lambda }} \cr} $$
$$\therefore $$ Wavelength of the first line, $${\lambda _L}$$ of the Lyman series is given by
$$\eqalign{
& \frac{1}{{{\lambda _L}}} = R\left( {1 - \frac{1}{4}} \right) = \frac{{36}}{{5\lambda }} \times \frac{3}{4} = \frac{{27}}{{5\lambda }} \cr
& \Rightarrow {\lambda _L} = \frac{{5\lambda }}{{27}} \cr} $$
115.
The radius of hydrogen atom in its ground state is $$5.3 \times {10^{ - 11}}m.$$ After collision with an electron it is found to have a radius of $$21.2 \times {10^{ - 11}}m.$$ What is the principal quantum number $$n$$ of the final state of the atom ?
Radii of Bohr's stationary orbit is given by
$$r = \frac{{{n^2}{h^2}}}{{4{\pi ^2}mk{e^2}Z}} \Rightarrow r \propto \frac{{{n^2}}}{Z}$$
Considering two situations of electrons,
$$ \Rightarrow \frac{{\left( {{r_f}} \right)}}{{\left( {{r_i}} \right)}} = \frac{{n_f^2}}{{n_i^2}}$$
For ground state $${n_i} = 1$$
$$\eqalign{
& \therefore \frac{{21.2 \times {{10}^{ - 11}}}}{{5.3 \times {{10}^{ - 11}}}} = n_f^2 \cr
& {\text{or}}\,\,n_f^2 = 4 \cr
& \therefore {n_f} = 2 \cr} $$
116.
The energy of electron in the nth orbit of hydrogen atom is expressed as $${E_n} = \frac{{ - 13.6}}{{{n^2}}}eV.$$ The shortest and longest wavelength of Lyman series will be
A
$$910\,\mathop {\text{A}}\limits^ \circ ,1213\,\mathop {\text{A}}\limits^ \circ $$
B
$$5463\,\mathop {\text{A}}\limits^ \circ ,7858\,\mathop {\text{A}}\limits^ \circ $$
C
$$1315\,\mathop {\text{A}}\limits^ \circ ,1530\,\mathop {\text{A}}\limits^ \circ $$
As $$\alpha $$-particles are doubly ionised helium $$H{e^{ + + }}$$ i.e, Positively charged and nucleus is also positively charged and we know that like charges repel each other.
118.
A Hydrogen atom and a $$L{i^{ + + }}$$ ion are both in the second excited state. If $${\ell _H}$$ and $${\ell _{Li}}$$ are their respective electronic angular momenta, and $${E_H}$$ and $${E_{Li}}$$ their respective energies, then
Wavelength of spectral lines are given by
$$\frac{1}{\lambda } = {z^2}R\left( {\frac{1}{{n_1^2}} - \frac{1}{{n_2^2}}} \right)$$
For last line of Balmer series,
$$\eqalign{
& {n_1} = 2\,\,{\text{and}}\,\,{n_2} = \infty \cr
& \Rightarrow \frac{1}{{{\lambda _B}}} = {z^2}R\left( {\frac{1}{{{2^2}}} - \frac{1}{{{\infty ^2}}}} \right) = \frac{R}{4}\,\,\left[ {\because z = 1} \right] \cr} $$
Similarly, for last line of Lyman series,
$$\eqalign{
& {n_1} = 1\,\,{\text{and}}\,\,{n_2} = \infty \cr
& \Rightarrow \frac{1}{{{\lambda _2}}} = {z^2}R\left( {\frac{1}{{{1^2}}} - \frac{1}{{{\infty ^2}}}} \right) = R \cr
& \therefore \frac{{\frac{1}{{{\lambda _B}}}}}{{\frac{1}{{{\lambda _L}}}}} = \frac{{\frac{R}{4}}}{R} = \frac{1}{4} \cr
& \Rightarrow \frac{{{\lambda _L}}}{{{\lambda _B}}} = \frac{1}{4} \Rightarrow \frac{{{\lambda _B}}}{{{\lambda _L}}} = 4 \cr} $$
120.
If potential energy between a proton and an electron is given by $$\left| U \right| = \frac{{k{e^2}}}{{2{R^3}}},$$ where $$e$$ is the charge of electron and $$R$$ is the radius of atom, then radius of Bohr's orbit is given by ($$h$$ = Planck's constant, $$k$$ = constant)
A
$$\frac{{k{e^2}m}}{{{h^2}}}$$
B
$$\frac{{6{\pi ^2}}}{{{n^2}}}\frac{{k{e^2}m}}{{{h^2}}}$$