Question

One mole of solid iron was vaporized in an oven at its boiling point of $$3443\,K$$  and enthalpy of vaporization of iron is $$344.3\,kJ\,mo{l^{ - 1}}.$$    The value of entropy vaporization $$\left( {{\text{in}}\,J\,mo{l^{ - 1}}} \right)$$   of iron is

A. 100  
B. 10
C. -100
D. 110
Answer :   100
Solution :
$$\eqalign{ & \Delta S = \frac{{\Delta H}}{T} \cr & = \frac{{344.3 \times {{10}^3}}}{{3443}} \cr & = 100\,J\,mo{l^{ - 1}} \cr} $$

Releted MCQ Question on
Physical Chemistry >> Chemical Thermodynamics

Releted Question 1

The difference between heats of reaction at constant pressure and constant volume for the reaction : $$2{C_6}{H_6}\left( l \right) + 15{O_{2\left( g \right)}} \to $$     $$12C{O_2}\left( g \right) + 6{H_2}O\left( l \right)$$     at $${25^ \circ }C$$  in $$kJ$$ is

A. $$-$$ 7.43
B. $$+$$ 3.72
C. $$-$$ 3.72
D. $$+$$ 7.43
Releted Question 2

For which change $$\Delta H \ne \Delta E\,:$$

A. $${H_{2\left( g \right)}} + {I_{2\left( g \right)}} \to 2HI\left( g \right)$$
B. $$HC{\text{l}} + NaOH \to NaC{\text{l}}$$
C. $${C_{\left( s \right)}} + {O_{{2_{\left( g \right)}}}} \to C{o_{{2_{\left( g \right)}}}}$$
D. $${N_2}\left( g \right) + 3{H_2}\left( g \right) \to 2N{H_3}\left( g \right)$$
Releted Question 3

$${\text{The}}\,\Delta H_f^0\,{\text{for}}\,C{O_2}\left( g \right),\,CO\left( g \right)\,$$     and $${H_2}O\left( g \right)$$   are $$-393.5,$$  $$-110.5$$  and $$ - 241.8\,kJ\,mo{l^{ - 1}}$$    respectively. The standard enthalpy change ( in $$kJ$$ ) for the reaction $$C{O_2}\left( g \right) + {H_2}\left( g \right) \to CO\left( g \right) + {H_2}O\left( g \right)\,{\text{is}}$$

A. 524.1
B. 41.2
C. -262.5
D. -41.2
Releted Question 4

In thermodynamics, a process is called reversible when

A. surroundings and system change into each other.
B. there is no boundary between system and surroundings.
C. the surroundings are always in equilibrium with the system.
D. the system changes into the surroundings spontaneously.

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Chemical Thermodynamics


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