Question
One mole of an ideal gas requires $$207\,J$$ heat to rise the temperature by $$10\,K$$ when heated at constant pressure. If the same gas is heated at constant volume to raise the temperature by the same $$10\,K,$$ the heat required is (Given the gas constant $$R = 8.3\,J/mol - K$$ )
A.
$$198.7\,J$$
B.
$$29\,J$$
C.
$$215.3\,J$$
D.
$$124\,J$$
Answer :
$$124\,J$$
Solution :
Molar specific heat of a substance is defined as the amount of heat required to raise the temperature of one gram mole of the substance through a unit degree.
$$\eqalign{
& {\text{As}}\,{\left( {dQ} \right)_p} = \mu {C_p}dT\,\,......\left( {\text{i}} \right)\,\left( {{\text{At}}\,{\text{constant pressure}}} \right) \cr
& {\text{and}}\,{\left( {dQ} \right)_V} = \mu {C_V}dT\,\,......\left( {{\text{ii}}} \right)\,\left( {{\text{At}}\,{\text{constant volume}}} \right) \cr
& {\text{Given,}}\,{\left( {dQ} \right)_p} = 207\,J \cr
& R = 8.3\,J/mol - K \cr
& dT = 10\,K \cr
& {\text{Putting value in Eq}}{\text{. }}\left( {\text{i}} \right) \cr
& 207 = 1 \times {C_p} \times 10 \cr
& \therefore {C_p} = 20.7\,J/kg \cr
& {\text{As}}\,{C_p} - {C_V} = R = 8.3 \cr
& {C_V} = 20.7 - 8.3 = 12.4\,J \cr
& \therefore {\left( {dQ} \right)_V} = 1 \times 12.4 \times 10 \cr
& = 124\,J \cr} $$