Question
Electronegativity of carbon atoms depends upon their state of hybridisation. In which of the following compounds, the carbon marked with asterisk is most electronegative?
A.
$$C{H_3} - C{H_2} - \mathop C\limits^ * {H_2} - C{H_3}$$
B.
$$C{H_3} - \mathop C\limits^ * H = CH - C{H_3}$$
C.
$$C{H_3} - C{H_2} - C \equiv \mathop C\limits^ * H$$
D.
$$C{H_3} - C{H_2} - CH = \mathop C\limits^ * {H_2}$$
Answer :
$$C{H_3} - C{H_2} - C \equiv \mathop C\limits^ * H$$
Solution :
The greater the $$s$$ character of the hybrid orbitals, the greater is the electronegativity. Thus, a carbon atom having an $$sp$$ hybrid orbital with $$50\% \,s$$ character is more electronegative than those possessing $$s{p^2}$$ or $$s{p^3}$$ hybridised orbitals .
The asterisk marked carbon in $$C{H_3} - C{H_2} - C \equiv \mathop C\limits^ * H$$ is $$sp$$ hybridised hence, it is most electronegative.