Question

Electronegativity of carbon atoms depends upon their state of hybridisation. In which of the following compounds, the carbon marked with asterisk is most electronegative?

A. $$C{H_3} - C{H_2} - \mathop C\limits^ * {H_2} - C{H_3}$$
B. $$C{H_3} - \mathop C\limits^ * H = CH - C{H_3}$$
C. $$C{H_3} - C{H_2} - C \equiv \mathop C\limits^ * H$$  
D. $$C{H_3} - C{H_2} - CH = \mathop C\limits^ * {H_2}$$
Answer :   $$C{H_3} - C{H_2} - C \equiv \mathop C\limits^ * H$$
Solution :
The greater the $$s$$  character of the hybrid orbitals, the greater is the electronegativity. Thus, a carbon atom having an $$sp$$  hybrid orbital with $$50\% \,s$$  character is more electronegative than those possessing $$s{p^2}$$  or $$s{p^3}$$  hybridised orbitals .
The asterisk marked carbon in $$C{H_3} - C{H_2} - C \equiv \mathop C\limits^ * H$$     is $$sp$$  hybridised hence, it is most electronegative.

Releted MCQ Question on
Organic Chemistry >> General Organic Chemistry

Releted Question 1

The bond order of individual carbon-carbon bonds in benzene is

A. one
B. two
C. between one and two
D. one and two alternately
Releted Question 2

Molecule in which the distance between the two adjacent carbon atoms is largest is

A. Ethane
B. Ethene
C. Ethyne
D. Benzene
Releted Question 3

Among the following, the compound that can be most readily sulphonated is

A. benzene
B. nitrobenzene
C. toluene
D. chlorobenzene
Releted Question 4

The compound 1, 2-butadiene has

A. only $$sp$$   hybridized carbon atoms
B. only $$s{p^2}$$ hybridized carbon atoms
C. both $$sp$$  and $$s{p^2}$$ hybridized carbon atoms
D. $$sp$$ , $$s{p^2}$$ and $$s{p^3}$$ hybridized carbon atoms

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