Question

Complete hydrolysis of cellulose gives

A. $$D$$ - ribose
B. $$D$$ - glucose  
C. $$L$$ - glucose
D. $$D$$ - fructose
Answer :   $$D$$ - glucose
Solution :
Cellulose is a linear polymer of $$\beta - D - $$  glucose in which $${C_1}$$  of one glucose unit is connected to $${C_4}$$  of the other through $$\beta - D$$  glucosidic linkage. It does not undergo hydrolysis easily. However on heating with dilute $${H_2}S{O_4}$$  under pressure. It does undergo hydrolysis to give only $$D - $$ glucose.
\[\left( {{C}_{6}}{{H}_{10}}{{O}_{5}} \right)n+n{{H}_{2}}O\xrightarrow{H+}\underset{D\text{-Glucose}}{\mathop{n{{C}_{6}}{{H}_{12}}{{O}_{6}}}}\,\]

Releted MCQ Question on
Organic Chemistry >> Biomolecules

Releted Question 1

The pair of compounds in which both the compounds give positive test with Tollen’s reagent is

A. Glucose and Sucrose
B. Fructose and Sucrose
C. Acetophenone and Hexanal
D. Glucose and Fructose
Releted Question 2

The two forms of $$D - $$ glucopyranose obtained from the solution of $$D - $$ glucose are called

A. Isomers
B. Anomers
C. Epimers
D. Enantiomers
Releted Question 3

Cellulose upon acetylation with excess acetic anhydride/ $${H_2}S{O_4}$$  (catalytic) gives cellulose triacetate whose structure is

A. Biomolecules mcq option image
B. Biomolecules mcq option image
C. Biomolecules mcq option image
D. Biomolecules mcq option image
Releted Question 4

The following carbohydrate is
Biomolecules mcq question image

A. a ketohexose
B. an aldohexose
C. an $$\alpha $$ - furanose
D. an $$\alpha $$ - pyranose

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Biomolecules


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