121.
For a linear plot of $$\log \,\left( {x/m} \right)$$ versus $$\log \,p$$ in a Freundlich adsorption isotherm, which of the following statements is correct? ( $$k$$ and $$n$$ are constants )
A
Only $$\frac{1}{n}$$ appears as the slope.
B
log $$\left( {\frac{1}{n}} \right)$$ appears as the intercept.
C
Both $$k$$ and $$\frac{1}{n}$$ appear in the slope term.
D
$$\frac{1}{n}$$ appears as the intercept.
Answer :
Only $$\frac{1}{n}$$ appears as the slope.
According to Freundlich adsorption isotherm
$$\log \frac{x}{m} = \log K + \frac{1}{n}\,\,\log \,P$$
Thus if a graph is plotted between $$\log \left( {\frac{x}{m}} \right)$$ and $$\log \,p$$ , a straight line will be obtained
The slope of the line is equal to $$\frac{1}{n}$$ and the intercept on $$\log \frac{x}{m}$$ axis will correspond to $$\log \,K.$$
122.
During dialysis
A
only solvent molecules can diffuse
B
solvent molecules, ions and colloidal particles can diffuse
C
all kinds of particles can diffuse through the semipermeable membrane
The principle of dialysis is based upon the fact that colloidal particles cannot pass through a parchment or cellophane membrane while the ions of the electrolyte can pass through it.
123.
The method usually employed for the precipitation of a colloidal solution is
126.
Given below are a few electrolytes, indicate which one among them will bring about the coagulation of a gold sol quickest and in the least of concentration?
A
$$NaCl$$
B
$$MgS{O_4}$$
C
$$A{l_2}{\left( {S{O_4}} \right)_3}$$
D
$${K_4}\left[ {Fe{{\left( {CN} \right)}_6}} \right]$$
Lyophobic sols are unstable, so they are stabilised by adding some lyophilic colloids which protect them from precipitation. Thus, lyophilic colloids are called protecting colloids. Their protecting power is expressed in terms of gold number. In other words, gold number can be defined as the minimum amount of lyophilic colloid in milligrams, which prevent the flocculation of $$10$$ $$mL$$ gold sol by the addition of $$1$$ $$mL$$ of $$10\% \,NaCl$$ solution.
NOTE
Lesser the gold number, higher is the protecting power.
128.
The correct statement for both the processes of physisorption and chemisorption is
A
both are endothermic
B
chemisorption is endothermic but physisorption is exothermic
C
both are exothermic
D
physisorption is endothermic but chemisorption is exothermic.