In $$bcc$$ unit cell, the number of atoms = 2
Thus, volume of atoms in unit cell $$\left( v \right) = 2 \times \frac{4}{3}\pi {r^3}$$
For $$bcc$$ structure $$\left( r \right) = \frac{{\sqrt 3 }}{4}a$$
$$\eqalign{
& \left( V \right) = 2 \times \frac{4}{3}\pi {\left( {\frac{{\sqrt 3 }}{8}a} \right)^3} \cr
& \,\,\,\,\,\,\,\,\,\, = \frac{{\sqrt 3 }}{8}\pi \,{a^3} \cr} $$
Volume of unit cell $$\left( V \right) = {a^3}$$
Percentage of volume occupied by unit cell
$$\eqalign{
& = \frac{{{\text{Volume of the atoms in unit cell}}}}{{{\text{Volume of unit cell}}}} \cr
& = \frac{{\frac{{\sqrt 3 }}{8}\pi \,{a^3}}}{{{a^3}}} \times 100 \cr
& = \frac{{\sqrt 3 }}{8}\pi \times 100 \cr
& = 68\% \cr} $$
Hence, the free space in $$bcc$$ unit cell $$ = 100 - 68 = 32\% $$
12.
The rate of diffusion of methane at a given temperature is twice that of a gas $$X.$$ The molecular weight of $$X$$ is
This figure clearly helps to establish the relation that force is directly proportional to area of contact and velocity gradient.
$$\eqalign{
& f \propto A,f \propto \frac{{du}}{{dz}} \cr
& \therefore f \propto A\frac{{du}}{{dz}};f = \eta A\frac{{du}}{{dz}} \cr} $$
Where, $$\eta = $$ coefficient of viscosity.
$$A = $$ Area of contact.
$$\frac{{du}}{{dz}} = $$ veIocity gradient.
14.
At $${100^ \circ }C$$ and $$1\,atm,$$ if the density of liquid water is $$1.0\,g\,c{m^{ - 3}}$$ and that of water vapour is $$0.0006\,g\,c{m^{ - 3}},$$ then the volume occupied by water molecules in 1 litre of steam at that temperature is
A gas is a collection of tiny particles separated from one another by large empty space and moving rapidly at random in all the directions. In the course of their motion, they collide with one another and also with the walls of the container. Due to frequent collisions, speeds and direction of motion of molecules keeps on changing. Thus, all the molecules in a sample of a gas do not have same speeds.
17.
According to the kinetic theory of gases, in an ideal gas, between two successive collisions a gas molecule travels
According to kinetic theory the gas molecules are in a state of constant rapid motion in all possible directions colloiding in a random manner with one another and with the walls of the container and between two successive collisions molecules travel in a straight line path but show haphazard motion due to collisions.
18.
Equal moles of hydrogen and oxygen gases are placed in container with a pin-hole through which both can escape. What fraction of the oxygen escapes in the time required for one-half of the hydrogen to escape?
Given, number of moles of hydrogen $$\left( {{n_{{H_2}}}} \right)$$ and that of oxygen $$\left( {{n_{{O_2}}}} \right)$$ are equal.
∴ We have, the relation between ratio of number of moles escaped and ratio of molecular mass.
$$\frac{{{n_{{O_2}}}}}{{{n_{{H_2}}}}} = \sqrt {\frac{{{M_{{H_2}}}}}{{{M_{{O_2}}}}}} $$
where, $$M$$ = Molecular mass of the molecule.
$$\eqalign{
& \Rightarrow \frac{{{n_{{O_2}}}}}{{{n_{{H_2}}}}} = \sqrt {\frac{2}{{32}}} \cr
& \Rightarrow \frac{{{n_{{O_2}}}}}{{{n_{{H_2}}}}} = \sqrt {\frac{1}{{16}}} \cr
& \Rightarrow \frac{{{n_{{O_2}}}}}{{0.5}} = \frac{1}{4} \cr
& \Rightarrow {n_{{O_2}}} = \frac{{0.5}}{4} = \frac{1}{8} \cr} $$
19.
The intermetallic compound $$LiAg$$ crystallises in cubic lattice in which both
lithium and silver have coordination number of eight. The crystal class is