81. In the reaction $$2FeC{l_3} + {H_2}S \to 2\,FeC{l_2} + 2\,HCl + S$$

A $$FeC{l_3}$$  acts as an oxidising agent
B Both $${H_2}S$$  are $$FeC{l_3}$$  are oxidised
C $$FeC{l_3}$$  is oxidised while $${H_2}S$$  is reduced
D $${H_2}S$$  acts as an oxidising agent.
Answer :   $$FeC{l_3}$$  acts as an oxidising agent
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82. Match the compounds given in column I with oxidation states of carbon given in column II and mark the apprapriate choice.
Column I Column II
a. $${C_6}{H_{12}}{O_6}$$ 1. + 3
b. $$CHC{l_3}$$ 2. − 3
c. $$C{H_3}C{H_3}$$ 3. + 2
d. $${\left( {COOH} \right)_2}$$ 4. 0

A a - 4, b - 3, c - 2 , d - 1
B a - 1, b - 2, c - 3 , d - 4
C a - 2, b - 3, c - 4 , d - 1
D a - 3, b - 2, c - 1, d - 4
Answer :   a - 4, b - 3, c - 2 , d - 1
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83. Which substance serves as reducing agent in the following reaction?
$$14{H^ + } + C{r_2}O_7^{2 - } + 3Ni \to $$      $$2C{r^{3 + }} + 7{H_2}O + 3N{i^{2 + }}$$

A $${H_2}O$$
B $$Ni$$
C $${H^ + }$$
D $$C{r_2}O_7^{2 - }$$
Answer :   $$Ni$$
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84. Arrange the oxides of nitrogen in increasing order of oxidation state of $$N$$  from +1 to +5.

A $${N_2}O < {N_2}{O_3} < N{O_2} < {N_2}{O_5} < NO$$
B $${N_2}O < NO < {N_2}{O_3} < N{O_2} < {N_2}{O_5}$$
C $${N_2}{O_5} < N{O_2} < {N_2}{O_3} < NO < {N_2}O$$
D $$NO < {N_2}O < N{O_2} < {N_2}{O_3} < {N_2}{O_5}$$
Answer :   $${N_2}O < NO < {N_2}{O_3} < N{O_2} < {N_2}{O_5}$$
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85. Which of the following statements is correct regarding redox reactions?

A An increase in oxidation number of an element is called reduction.
B A decrease in oxidation number of an element is called oxidation.
C A reagent which lowers the oxidation number of an element in a given substance is reductant.
D A reagent which increases the oxidation number of an element in a given substance is reductant.
Answer :   A reagent which lowers the oxidation number of an element in a given substance is reductant.
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86. Write the stoichiometric coefficient for the following reaction :
$$x{I_2} + yO{H^ - } \to IO_3^ - + z{I^ - } + 3{H_2}O$$
$$x$$ $$y$$ $$z$$
(a) 6 3 5
(b) 3 2 3
(c) 3 6 5
(d) 3 3 3

A (a)
B (b)
C (c)
D (d)
Answer :   (c)
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87. Which of the following species has an atom with +6 oxidation state?

A $$MnO_4^ - $$
B $${\left[ {Cr{{\left( {CN} \right)}_6}} \right]^{3 - }}$$
C $${\left[ {Ni{F_6}} \right]^{2 - }}$$
D $$Cr{O_2}C{l_2}$$
Answer :   $$Cr{O_2}C{l_2}$$
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88. Given below are few statements regarding electrode potentials. Mark the correct statements.
(i) The potential associated with each electrode is known as electrode potential.
(ii) A negative $${E^ \circ }$$ means that the redox couple is a stronger reducing agent than $$\frac{{{H^ + }}}{{{H_2}}}$$  couple.
(iii) A positive $${E^ \circ }$$ means that the redox couple is a weaker reducing agent than $$\frac{{{H^ + }}}{{{H_2}}}$$  couple.

A (i) and (ii)
B (i) and (iii)
C (ii) and (iii)
D (i), (ii) and (iii)
Answer :   (i), (ii) and (iii)
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89. In the reaction $$3Mg + {N_2} \to M{g_3}{N_2}$$

A magnesium is reduced
B magnesium is oxidized
C nitrogen is oxidized
D None of these
Answer :   magnesium is oxidized
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90. In which of the following compounds carbon is in highest oxidation state?

A $$C{H_3}Cl$$
B $$CC{l_4}$$
C $$CHC{l_3}$$
D $$C{H_2}C{l_2}$$
Answer :   $$CC{l_4}$$
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