11. Which of the following is not an example of disproportionation reaction?

A $$4ClO_3^ - \to C{l^ - } + 3ClO_4^ - $$
B $$2{H_2}{O_2} \to 2{H_2}O + {O_2}$$
C $$2N{O_2} + 2O{H^ - } \to $$     $$NO_2^ - + NO_3^ - + {H_2}O$$
D $$TiC{l_4} + 2Mg \to Ti + 2MgC{l_2}$$
Answer :   $$TiC{l_4} + 2Mg \to Ti + 2MgC{l_2}$$
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12. In the reaction : $$C + 4HN{O_3} \to C{O_2} + 2{H_2}O + 4N{O_2}$$
$$HN{O_3}$$  act as

A an oxidizing agent
B an acid
C an acid as well as oxidizing agent
D a reducing agent.
Answer :   an oxidizing agent
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13. Among $$N{H_3},HN{O_3},Na{N_3}$$     and $$M{g_3}{N_2}$$  the number of molecules having nitrogen in negative oxidation state is

A 1
B 2
C 3
D 4
Answer :   3
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14. Oxidation state of sulphur in anions $${S_2}O_3^{2 - },{S_2}O_4^{2 - }$$   and $${S_2}O_6^{2 - }$$  increases in the orders :

A $${S_2}O_6^{2 - } < {S_2}O_4^{2 - } < SO_3^{2 - }$$
B $$SO_6^{2 - } < {S_2}O_4^{2 - } < {S_2}O_6^{2 - }$$
C $${S_2}O_4^{2 - } < SO_3^{2 - } < {S_2}O_6^{2 - }$$
D $${S_2}O_4^{2 - } < {S_2}O_6^{2 - } < SO_3^{2 - }$$
Answer :   $${S_2}O_4^{2 - } < SO_3^{2 - } < {S_2}O_6^{2 - }$$
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15. The standard electrode potentials of four elements $$A, B, C$$   and $$D$$ are –3.05, –1.66, –0.40 and +0.80. The highest chemical reactivity will be exhibited by :

A $$A$$
B $$B$$
C $$C$$
D $$D$$
Answer :   $$A$$
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16. $$a{K_2}C{r_2}{O_7} + bKCl + c{H_2}S{O_4} \to $$       $$xCr{O_2}C{l_2} + yKHS{O_4} + z{H_2}O$$
The above equation balances when

A $$a = 2,b = 4,c = 6\,\,{\text{and}}\,x = 2,y = 6,z = 3$$
B $$a = 4,b = 2,c = 6\,{\text{and}}\,x = 6,y = 2,z = 3$$
C $$a = 6,b = 4,c = 2\,{\text{and}}\,x = 6,y = 3,z = 2$$
D $$a = 1,b = 4,c = 6\,{\text{and}}\,x = 2,y = 6,z = 3$$
Answer :   $$a = 1,b = 4,c = 6\,{\text{and}}\,x = 2,y = 6,z = 3$$
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17. Identify the compounds which are reduced and oxidised in the following reaction :
$$3{N_2}{H_4} + 2BrO_3^ - \to $$     $$3{N_2} + 2B{r^ - } + 6{H_2}O$$

A $${N_2}{H_4}$$  is oxidised and $$BrO_3^ - $$  is reduced.
B $$BrO_3^ - $$  is oxidised and $${N_2}{H_4}$$  is reduced.
C $$BrO_3^ - $$  is both reduced and oxidised.
D $${N_2}{H_4}$$  is both reduced and oxidised.
Answer :   $${N_2}{H_4}$$  is oxidised and $$BrO_3^ - $$  is reduced.
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18. Which of the following is not a rule for calculating oxidation number?

A For ions, oxidation number is equal to the charge on the ion.
B The oxidation number of oxygen is -2 in all of its compounds.
C The oxidation number of fluorine is -1 in all of its compounds.
D Oxidation number of hydrogen is +1 except in binary hydrides of alkali metals and alkaline earth metals where it is -1.
Answer :   The oxidation number of oxygen is -2 in all of its compounds.
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19. Using the standard electrode potential, find out the pair between which redox reaction is not feasible. $${E^ \circ }$$ values : $$\frac{{F{e^{3 + }}}}{{F{e^{2 + }}}} = + 0.77;\frac{{{I_2}}}{{{I^ - }}} = + 0.54;$$      $$\frac{{C{u^{2 + }}}}{{Cu}} = + 0.34;\frac{{A{g^ + }}}{{Ag}} = + 0.80\,V$$

A $$F{e^{3 + }}\,{\text{and}}\,\,{I^ - }$$
B $$A{g^ + }\,{\text{and}}\,\,Cu$$
C $$F{e^{3 + }}\,{\text{and}}\,\,Cu$$
D $$Ag\,{\text{and}}\,\,F{e^{3 + }}$$
Answer :   $$Ag\,{\text{and}}\,\,F{e^{3 + }}$$
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20. In the reaction : $$C{l_2} + O{H^ - } \to C{l^ - } + ClO_4^ - + {H_2}O$$

A chlorine is oxidised
B chlorine is reduced
C chlorine is oxidised as well as reduced
D chlorine is neither oxidised nor reduced
Answer :   chlorine is oxidised as well as reduced
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