151. Which of the following statements is not true?

A In a chemical reaction, oxidation is always accompanied by reduction.
B When a negative ion changes to neutral species, the process is oxidation.
C Oxidising agent has a tendency to lose electrons.
D Conversion of Conversion of $$MnO_4^{2 - }$$  to $$MnO_4^ - $$  is oxidation.
Answer :   Oxidising agent has a tendency to lose electrons.
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152. In the conversion of $$B{r_2}$$  to $$BrO_3^ - ,$$  the oxidation state of $$Br$$  changes from

A +1 to +5
B 0 to -3
C +2 to +5
D 0 to +5
Answer :   0 to +5
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153. When $$Mn{O_2}$$  salt is fused with a mixture of $$KN{O_3}$$  and solid $$KOH$$  the oxidation number of $$Mn$$  changes from + 4 to

A + 4
B + 3
C + 6
D + 7
Answer :   + 6
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154. Which of the following is not a redox reaction?

A $${P_4} + 3O{H^ - }3{H_2}O \to P{H_3} + 3{H_2}PO_2^ - $$
B $$Na + {H_2}O \to NaOH + \frac{1}{2}{H_2}$$
C $$CaC{O_3} \to CaO + C{O_2}$$
D $${V_2}{O_5} + 5Ca \to 2V + 5CaO$$
Answer :   $$CaC{O_3} \to CaO + C{O_2}$$
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155. In the balanced chemical reaction $$IO_3^ - + a{I^ - } + b{H^ - } \to c{H_2}O + d{I_2}$$
$$a, b, c$$  and $$d,$$ respectively, correspond to

A 5, 6, 3, 3
B 5, 3, 6, 3
C 3, 5, 3, 6
D 5, 6, 5, 5
Answer :   5, 6, 3, 3
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156. Which of the following reactions shows the reducing property of $$S{O_2}?$$
$$\left( {\text{i}} \right)C{l_2} + S{O_2} \to S{O_2}C{l_2}$$
$$\left( {{\text{ii}}} \right)2{H_2}S + S{O_2} \to 3S + 2{H_2}O$$
$$\left( {{\text{iii}}} \right)2FeC{l_3} + S{O_2} + 2{H_2}O \to $$       $$2FeC{l_2} + {H_2}S{O_4} + 2HCl$$
$$\left( {{\text{iv}}} \right)S{O_2} + {H_2}O \to {H_2}S{O_3}$$

A (i) only
B (ii) and (iii)
C (ii) and (iv)
D (i), (ii) and (iv)
Answer :   (ii) and (iii)
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157. Which of the following elements does not show disproportionation tendency?

A $$Cl$$
B $$Br$$
C $$F$$
D $$I$$
Answer :   $$F$$
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158. Which of the following represents a redox reaction?

A $$NaOH + HCl \to NaCl + {H_2}O$$
B $$BaC{l_2} + {H_2}S{O_4} \to BaS{O_4} + 2HCl$$
C $$CuS{O_4} + 2{H_2}O \to Cu{\left( {OH} \right)_2} + {H_2}S{O_4}$$
D $$Zn + 2HCl \to ZnC{l_2} + {H_2}$$
Answer :   $$Zn + 2HCl \to ZnC{l_2} + {H_2}$$
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159. For the reaction : $${I^ - } + ClO_3^ - + {H_2}S{O_4} \to $$     $$C{l^ - } + HSO_4^ - + {I_2}$$
The incorrect statement in the balanced equation is

A stoichiometric coefficient of $$HSO_4^ - $$  is 6
B iodide is oxidised
C sulphur is reduced
D $${H_2}O$$  is one of the products
Answer :   sulphur is reduced
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160. Oxidation number of sulphur in peroxomono-sulphuric acid $$\left( {{H_2}S{O_5}} \right)$$  is

A + 4
B + 2
C + 6
D - 2
Answer :   + 6
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