142.
Which of the following is correct code for $$x$$ and $$y$$ in the following reaction.
(i) $$x =$$ oxidation reaction, $$y =$$ reduction reaction
(ii) $$x =$$ gain of two electrons, $$y =$$ loss of two electrons,
(iii) $$x =$$ reduction reaction, $$y =$$ oxidation reaction
(iv) $$x =$$ loss of two electrons, $$y =$$ gain of two electrons
(A) $${\left( {N\mathop {{H_4}}\limits^{ + 1} } \right)_2}{S_2}{O_8}^{2 - }$$
∴ Oxidation state of $$S = + 6$$
( Since $${S_2}{O_8}^{2 - }$$ has one peroxide bond )
(B) Oxidation state of $$Os = + 8$$
(C) Oxidation state of $$S$$ in $$\,{H_2}S{O_5} = + 6$$
( Since it has one peroxide bond )
(D) $${K^{1 + }}{O_2}^{1 - },$$ oxidation state of $$O = - \frac{1}{2}$$
145.
The values of coefficients to balance the following reaction are $$Cr{\left( {OH} \right)_3} + Cl{O^ - } + O{H^ - } \to $$ $$CrO_4^{2 - } + C{l^ - } + {H_2}O$$