If we assume the atom to be hydrogen like, energy of $${n^{th}}$$ energy level
$${E_n} = - \frac{{{E_1}}}{{{n^2}}}$$
where $${{E_1}}$$ is energy of first energy level
$$\eqalign{
& {E_2} = - \frac{{{E_1}}}{{{2^2}}} \cr
& = - \frac{{{E_1}}}{4} \cr
& = \frac{{ - 21.79 \times {{10}^{ - 12}}}}{4} \cr
& = - 5.447 \times {10^{ - 12}}erg\,\,per\,\,atom. \cr} $$
62.
Arrange the electromagnetic radiations $$a, b, c, d$$ and $$e$$ in increasing order of energy. Frequencies of $$a, b$$ and $$c$$ are $${10^{15}},{10^{14}}$$ and $${10^{17}}$$ respectively whereas wavelength of $$(d)$$ and $$(e)$$ are $$350\,nm$$ and $$100\,nm$$ respectively ?
According to Hund’s rule of maximum multiplicity, An orbital can accommodate a
maximum number of 2 electrons of exactly opposite spin. Hence, option (A) is correct. Caution Remember, maximum number of electrons in an orbital do not depend upon the quantum numbers as given in the question.
66.
Which one is not in agreement with Bohr's model of the atom ?
Bohr's model of an atom describes orbit as a clearly defined path and this could be only possible when both position and the velocity of the electron are known exactly at the same time. This is not possible according to Heisenberg uncertainty principle.
67.
Electromagnetic radiation with maximum wavelength is :
TIPS/Formulae : The following is the increasing order of wavelength or decreasing order of energy of electromagnetic radiations :
Among given choices radiowaves have maximum wavelength.
68.
Consider the following sets of quantum numbers.
$$n$$
$$l$$
$$m$$
$$s$$
(i)
3
0
0
$$ + \frac{1}{2}$$
(ii)
2
2
1
$$ + \frac{1}{2}$$
(iii)
4
3
−2
$$ - \frac{1}{2}$$
(iv)
1
0
−1
$$ - \frac{1}{2}$$
(v)
3
2
3
$$ + \frac{1}{2}$$
Which of the following sets of quantum number is not possible?
The value of $$l$$ varies from 0 to $$(n - 1)$$ and the value of $$m$$ varies from $$- l$$ to $$+l$$ through zero.
The value of $$'s'\,\, \pm \,\,\frac{1}{2}$$ which signifies the spin of electron. The correct sets of quantum number are following:
$$n$$
$$l$$
$$m$$
$$s$$
(ii)
2
1
1
$$ - \frac{1}{2}$$
(iv)
1
0
0
$$ - \frac{1}{2}$$
(v)
3
2
2
$$ + \frac{1}{2}$$
69.
The uncertainty in momentum of an electron is $$1 \times {10^{ - 5}}kg/ms.$$ The uncertainty in its position will be
$$\left( {{\text{Given,}}\,h = 6.62 \times {{10}^{ - 34}}kg\,\,{m^2}/s} \right)$$
The possible quantum numbers for $$4f$$ electron are
$$\eqalign{
& n = 4,\, \cr
& l = 3,\, \cr
& m = - 3,\, - 2 - 1,\,\,0,\,\,1,\,\,2,\,\,3 \cr
& s = \pm \frac{1}{2} \cr} $$