261.
If the nitrogen atom had electronic configuration $$1{s^7}$$ it would have energy lower than that of the normal ground state configuration $$1{s^2}2{s^2}2{p^3}$$ because the electrons would be closer to the nucleus. Yet $$1{s^7}$$ is not observed. It violates
$$ns$$ orbital has $$\left( {n - 1} \right)$$ nodes.
263.
Uncertainty in position of an electron ( mass of an electron is $$ = 9.1 \times {10^{ - 28}}g$$ ) moving with a velocity of $$3 \times {10^4}cm/s$$ accurate upto $$0.001\% $$ will be ( use $$\frac{h}{{4\pi }}$$ in uncertainty expression where $$h = 6.626 \times {10^{ - 27}}erg\,s$$ )
Species having same number of electrons are isoelectronic calculating the number of electrons in each species given here, we get.
$$\eqalign{
& C{N^ - }\left( {6 + 7 + 1 = 14} \right);\,{N_2}\left( {7 + 7 = 14} \right); \cr
& O_2^{2 - }\left( {8 + 8 + 2 = 18} \right);\,C_2^{2 - }\left( {6 + 6 + 2 = 14} \right); \cr
& O_2^ - \left( {8 + 8 + 1 = 17} \right);\,N{O^ + }\left( {7 + 8 - 1 = 14} \right) \cr
& CO\left( {6 + 8 = 14} \right);\,NO\left( {7 + 8 = 15} \right) \cr} $$
From the above calculation we find that all the species listed in choice (B) have 14 electrons each so it is the correct answer.
265.
Two electrons occupying the same orbital are distinguished by
Two electrons occupying the same orbital has
equal spin but the directions of their spin are
opposite. Hence, spin quantum number, $$s,$$ ( represented $$ + \frac{1}{2}\,and - \frac{1}{2}$$ ) distinguishes them.
266.
$$P$$ is the probability of finding the $$1s$$ electron of hydrogen atom in a spherical shell of infinitesimal thickness, $$dr,$$ at a distance r from the nucleus. The volume of this shell is $${4_\pi }{r^2}dr.$$ The qualitative sketch of the dependence of $$P$$ on $$r$$ is
Radial probability function curve for $$1s$$ is (D).
$${\text{Here}}\,P\,{\text{is}}\,\,4\pi {r^2}{R^2}.$$
267.
The dissociation energy of $${H_2}$$ is $$430.53\,kJ\,mo{l^{ - 1}}.$$ If hydrogen is dissociated by illumination with radiation of wavelength $$253.7\,nm$$ the fraction of the radiant energy which will be converted into kinetic energy is given by
TIPS/Formulae : The element having highest tendency to accept the electron will be most electronegative element.
Configuration $$n{s^2},\,n{p^5}$$ means it requires only one electron to attain nearest noble gas configuration. So, it will be most electronegative element among given choices.
270.
The energy of a photon is given as $$3.03 \times {10^{ - 19}}J.$$ The wavelength of the photon is