More is the stability, lower is the heat of combustion ( See Baeyer’s strain theory ). Cyclohexane is more stable.
97.
Nitrobenzene can be prepared from benzene by using a mixture of $$conc.$$ $$HN{O_3}$$ and $$conc.$$ $${H_2}S{O_4}.$$ In the mixture, nitric acid acts as a/an
$$Conc.$$ $${H_2}S{O_4}$$ and $$conc.$$ $$HN{O_3}$$ react in the following manner
\[\begin{align}
& \underset{\text{Base}}{\mathop{HN{{O}_{3}}}}\,+\underset{\text{Acid}}{\mathop{{{H}_{2}}S{{O}_{4}}}}\,\to {{H}_{2}}NO_{3}^{+}+HSO_{4}^{-} \\
& {{H}_{2}}NO_{3}^{+}\to \underset{\begin{align}
& \,\,\,\,\,\,\,\,\text{Nitronium}\text{.} \\
& \,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\text{ion}\text{.} \\
& \text{Attacking species} \\
& \,\,\,\,\,\,\text{(electrophile)} \\
\end{align}}{\mathop{NO_{2}^{+}}}\,+{{H}_{2}}O \\
\end{align}\]
Hence, in this reaction $$HN{O_3}$$ acts as a base and $${H_2}S{O_4}$$ as an acid.
98.
The bond energy $$\left( {{\text{in}}\,\,kcal\,\,mo{l^{ - 1}}} \right)$$ of a $$C - C$$ single bond is approximately
3-Methylhexane can yield seven different monochlorinated products on chlorination.
\[{{H}_{3}}C-C{{H}_{2}}-C{{H}_{2}}\overset{\begin{smallmatrix}
\,\,\,C{{H}_{3}} \\
|\,\,\,\,
\end{smallmatrix}}{\mathop{-CH-}}\,C{{H}_{2}}-C{{H}_{3}}\]
Each carbon atom on chlorination givesa different product.