81. Which of the following cannot be represented by resonance structures ?

A Dimethyl ether
B Nitrate anion
C Carboxylate anion
D Toluene
Answer :   Dimethyl ether
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82. Which of the following IUPAC names is not correctly matched?

A General Organic Chemistry mcq option image - Cyclopentane
B General Organic Chemistry mcq option image - Chlorocyclohexane
C General Organic Chemistry mcq option image - 1, 1-dimethylcyclohexane
D General Organic Chemistry mcq option image -3-Nitrocyclohexene
Answer :   General Organic Chemistry mcq option image - 1, 1-dimethylcyclohexane
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83. The change in the state of hybridization of the asterisked carbon in the following reaction.
\[C{{H}_{3}}\overset{*}{\mathop{C}}\,N\xrightarrow{{{H}_{2}}O}C{{H}_{3}}\overset{*}{\mathop{C}}\,ON{{H}_{2}}\]      is

A $$s{p^3}\,{\text{to}}\,s{p^2}$$
B $$s{p^3}\,{\text{to}}\,sp$$
C $$sp\,{\text{to}}\,s{p^2}$$
D $$s{p^2}\,{\text{to}}\,s{p^3}$$
Answer :   $$sp\,{\text{to}}\,s{p^2}$$
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84. How many stereoisomers does this molecule have?
$$C{H_3}CH = CHC{H_2}CHBrC{H_3}$$

A 4
B 6
C 8
D 2
Answer :   4
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85. Which of the following is the correct order of acidity of carboxylic acids?
$$\left( {\text{i}} \right)C{l_3}CCOOH > C{l_2}CHCOOH$$       $$ > ClC{H_2}COOH$$
$$\left( {{\text{ii}}} \right)C{H_3}C{H_2}COOH > $$     $${\left( {C{H_3}} \right)_2}CHCOOH > {\left( {C{H_3}} \right)_3}CCOOH$$
$$\left( {{\text{iii}}} \right){F_2}CHCOOH > FC{H_2}COOH$$       $$ > ClC{H_2}COOH$$

A (i) and (ii)
B (ii) and (iii)
C (i) and (iii)
D (i), (ii) and (iii)
Answer :   (i), (ii) and (iii)
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86. Out of the following compounds, which will have a zero dipole moment?

A 1, 1 - dichloroethylene
B $$cis$$ - 1, 2 - dichloroethylene
C $$trans$$  - 1, 2 - dichloroethylene
D None of these compounds
Answer :   $$trans$$  - 1, 2 - dichloroethylene
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87. Arrange in the order of increasing acidity.
General Organic Chemistry mcq question image

A III < I < II
B I < III < II
C III < II < I
D II < I < III
Answer :   II < I < III
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88. Select the most stable carbocation amongst the following

A General Organic Chemistry mcq option image
B General Organic Chemistry mcq option image
C General Organic Chemistry mcq option image
D General Organic Chemistry mcq option image
Answer :   General Organic Chemistry mcq option image
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89. Which of the following orders is correct for heat of hydrogenation of these compounds ?
General Organic Chemistry mcq question image

A I > II > III
B III > II > I
C II > III > I
D III > I > II
Answer :   II > III > I
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90. The masses of carbon, hydrogen and oxygen in an organic compound are in the ratio 6 : 1 : 8 respectively. Which of the following pairs of formulae correspond to above information?

A $$C{H_2}O{\text{ and }}C{H_3}CHO$$
B $$C{H_2}O{\text{ and }}{C_3}{H_6}O$$
C $${C_3}{H_6}O{\text{ and }}{C_2}{H_6}{O_2}$$
D $${C_3}{H_6}{O_3}{\text{ and }}HCHO$$
Answer :   $${C_3}{H_6}{O_3}{\text{ and }}HCHO$$
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