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83.
The change in the state of hybridization of the asterisked carbon in the following reaction.
\[C{{H}_{3}}\overset{*}{\mathop{C}}\,N\xrightarrow{{{H}_{2}}O}C{{H}_{3}}\overset{*}{\mathop{C}}\,ON{{H}_{2}}\] is
$${C^*} = $$ asymmetric carbon
Number of optical isomers $$ = {2^n}$$
where, $$n = $$ number of asymmetric carbon atoms $$ = {2^1} = 2$$
Number of geometrical isomers $$ = {2^n}$$
where, $$n = $$ number of double bonds $$ = {2^1} = 2$$
Hence, total number of stereoisomers = Total optical isomers + Total geometrical isomers = 2 + 2 = 4
85.
Which of the following is the correct order of acidity of carboxylic acids?
$$\left( {\text{i}} \right)C{l_3}CCOOH > C{l_2}CHCOOH$$ $$ > ClC{H_2}COOH$$
$$\left( {{\text{ii}}} \right)C{H_3}C{H_2}COOH > $$ $${\left( {C{H_3}} \right)_2}CHCOOH > {\left( {C{H_3}} \right)_3}CCOOH$$
$$\left( {{\text{iii}}} \right){F_2}CHCOOH > FC{H_2}COOH$$ $$ > ClC{H_2}COOH$$
The strength of the acid increases with the inductive effect of the electronegative group attached to it ( $$-I$$ effect ). The strength of the acid decreases with the presence of electron releasing group.
86.
Out of the following compounds, which will have a zero
dipole moment?
Structure (B) is a $${3^ \circ }$$ carbocation, while (A) is $${2^ \circ }$$ and (C) and (D) are $${1^ \circ }$$ carbocations; thus (B) is the most stable.
89.
Which of the following orders is correct for heat of hydrogenation of these compounds ?
$${\text{Heat of hydrogenation}} \propto \frac{1}{{{\text{Stability of alkene}}}}.$$
90.
The masses of carbon, hydrogen and oxygen in an organic compound are in the ratio 6 : 1 : 8 respectively. Which of the following pairs of formulae correspond to above information?
In $${C_3}{H_6}{O_3},$$ mass of 3 $$C$$ - atoms = 12 × 3 = 36
mass of 6 $$H$$ - atoms = 1 × 6 = 6
mass of 3 $$O$$ - atoms = 16 × 3 = 48
∴ Ratio of masses of $$C : H : O$$ is 36 : 6 : 48 or 6 : 1 : 8.
In $$HCHO,$$ mass of 1 $$C$$ - atom = 12
mass of 2 $$H$$ - atoms = 2
mass of 1 $$O$$ - atom = 16
∴ Ratio of masses of $$C : H : O$$ is 12 : 2 : 16 or 6 : 1 : 8.