The process of separation of a racemic mixture into $$d-$$ or $$l-$$ forms (enantiomers) is called resolution. The racemic mixture of enantiomers is resolved by treating with an enantiomers of some chiral compound. The products are diastereomers which can be separated by usual methods such as recrystallisation, chromatography, etc.
Hyperconjugation occurs through the $$H$$ - atoms present on the carbon atom next to the double bond i.e. $$\alpha $$ - hydrogen atoms.
There is no $$\alpha - H$$ in the structures I and II.
So, hyperconjugation occurs in structure III only i.e.
125.
Which of the following represents 3-methylpenta-1, 3-diene?
A
$$C{H_2} = CH{\left( {C{H_2}} \right)_2}C{H_3}$$
B
$$C{H_2} = CHCH\left( {C{H_3}} \right)C{H_2}C{H_3}$$
C
$$C{H_3}CH = C\left( {C{H_3}} \right)CH = C{H_2}$$
NOTE: This is an example of \[{{S}_{N}}1\] reaction involving carbocation as intermediate.
This carbocation is especially stabilised through resonance in which \[-\underset{\centerdot \,\centerdot }{\overset{\centerdot \,\centerdot }{\mathop{O}}}\,-C{{H}_{3}}\] group acts as a good electron donor.
130.
The process of separation of an organic compound from its aqueous solution by shaking with a suitable solvent is termed solvent extraction or differential extraction.
The organic compound present in the aqueous layer moves to the organic solvent because
A
the organic substance is more soluble in the organic solvent
B
organic compound being lighter moves in the upper layer
C
organic solvent is insoluble in water hence organic compound moves up
D
from the supersaturated aqueous solution the solute starts diffusing
Answer :
the organic substance is more soluble in the organic solvent