185.
The purity of $${H_2}{O_2}$$ in a given sample is $$85\% .$$ Calculate the weight of impure sample of $${H_2}{O_2}$$ which requires $$10\,mL$$ of $$\frac{M}{5}\,KMn{O_4}$$ solution in titration in acidic medium
Heavy water is $${D_2}O$$ hence
number of electrons $$ = 2 + 8 = 10$$
number of protons $$ = 10$$
Atomic mass of $${D_2}O = 4 + 16 = 20$$
hence number of neutron = Atomic mass – number of protons
$$ = 20 - 10 = 10$$
187.
The normality and volume strength of a solution made by mixing $$1.0\,L$$ each of 5.6 volume and 11.2 volume $${H_2}{O_2}$$ solution are :
Polyphosphates like sodium hexametaphosphate (calgon) form soluble complexes with cations like $$C{a^{2 + }}$$ and $$M{g^{2 + }}$$ present in hard water and hence used as water softening agents.
$$N{a_6}{P_6}{O_{18}} \to 2N{a^ + } + N{a_4}{P_6}O_{18}^{2 - }$$
$${M^{2 + }} + N{a_4}{P_6}O_{18}^{2 - } \to $$ $${\left[ {N{a_2}M{P_6}{O_{18}}} \right]^{2 - }} + 2N{a^ + }$$
190.
Choose the correct option as directed.
A
$$CsH < KH < NaH < LiH$$ ( Order of reducing strength )
B
$${H_2}O < N{H_3} < C{H_4}$$ ( Order of dipole moment )
C
$$P{H_3} < As{H_3} < N{H_3} < Sb{H_3}$$  (Order of boiling point)
D
$$X - H - X,X = O > F > N > S > Cl$$ ( Order of strength of $$H$$ - bonding )
$$CsH > KH > NaH > LiH$$
The reducing strength of the alkali metal hydrides increases down the group.
$$C{H_4} < N{H_3} < {H_2}O$$
Dipole moment depends upon the difference between the electronegativities of the bonded atoms, and the internuclear separation.
$$P{H_3} < As{H_3} < N{H_3} < Sb{H_3}$$
Boiling point increases with an increase in molecular mass,
$$N{H_3}$$ being an exception because of strong hydrogen bonding.
$$Cl < S < N < O < F$$
The strength of hydrogen bonding depends upon the electronegativity and the size. Higher electronegativity and smaller size increases the strength of hydrogen bonding.