Question

\[\begin{align} & M{{g}_{3}}{{B}_{2}}\xrightarrow{HC{{l}_{\left( aq \right)}}}\left[ X \right]+MgC{{l}_{2}} \\ & \left[ X \right]+{{H}_{2}}O\xrightarrow{HC{{l}_{\left( aq \right)}}}\left[ Y \right]+{{H}_{2}} \\ \end{align}\]
For $$\left[ X \right]$$ and $$\left[ Y \right]$$ the incorrect choice is

A. $$\left[ X \right]$$ is $${B_2}{H_6}$$  and $$\left[ Y \right]$$ is $${H_3}B{O_3}$$
B. $$\left[ X \right]$$ with air and $$\left[ Y \right]$$ on strong heating ( red heat ) give same compound
C. In $$\left[ Y \right],$$ boron completes its octet by removing $${H^ + }$$ from water molecule
D. None of these  
Answer :   None of these
Solution :
\[\begin{align} & M{{g}_{3}}{{B}_{2}}+6HC{{l}_{\left( aq \right)}}\to \underset{\left( X \right)}{\mathop{{{B}_{2}}{{H}_{6}}}}\,+3MgC{{l}_{2}} \\ & \underset{\left( X \right)}{\mathop{{{B}_{2}}{{H}_{6}}}}\,+6{{H}_{2}}O\to \underset{\left( Y \right)}{\mathop{2{{H}_{3}}B{{O}_{3}}}}\,+6{{H}_{2}} \\ & \underset{\left( X \right)}{\mathop{{{B}_{2}}{{H}_{6}}}}\,+3{{O}_{2}}\to {{B}_{2}}{{O}_{3}}+3{{H}_{2}}O \\ & \underset{\left( Y \right)}{\mathop{{{H}_{3}}B{{O}_{3}}}}\,\xrightarrow{\Delta }{{B}_{2}}{{O}_{3}} \\ \end{align}\]
In $$Y,B$$  completes it octet by removing \[{{H}^{+}}\] from water molecule.

Releted MCQ Question on
Inorganic Chemistry >> P - Block Elements

Releted Question 1

The reddish brown coloured gas formed when nitric oxide is oxidised by air is

A. $${N_2}{O_5}$$
B. $${N_2}{O_4}$$
C. $$N{O_2}$$
D. $${N_2}{O_3}$$
Releted Question 2

The temporary hardness of water due to calcium carbonate can be removed by adding —

A. $$CaC{O_3}$$
B. $$Ca{\left( {OH} \right)_2}\,$$
C. $$CaC{l_2}$$
D. $$\,HCl$$
Releted Question 3

Which of the following is most stable to heat

A. $$HCl$$
B. $$HOCl$$
C. $$HBr$$
D. $$HI$$
Releted Question 4

White $$P$$ reacts with caustic soda. The products are $$P{H_3}$$ and $$Na{H_2}P{O_2}.$$   This reaction is an example of

A. Oxidation
B. Reduction
C. oxidation and reduction
D. Neutralisation

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P - Block Elements


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