Question

Aniline in a set of the following reactions yielded a coloured product $$Y.$$
Organic Compounds Containing Nitrogen mcq question image \[\xrightarrow[\left( 273-278K \right)]{\frac{NaN{{O}_{2}}}{HCl}}X\xrightarrow{N,\,N\text{-dimethylaniline}}Y\]
The structure of $$Y$$ would be

A. Organic Compounds Containing Nitrogen mcq option image  
B. Organic Compounds Containing Nitrogen mcq option image
C. Organic Compounds Containing Nitrogen mcq option image
D. Organic Compounds Containing Nitrogen mcq option image
Answer :   Organic Compounds Containing Nitrogen mcq option image
Solution :
Key Idea $$\frac{{NaN{O_2}}}{{HCl}}$$   causes diazotisation of $$ - N{H_2}$$  group and the diazonium chloride gives a coupling product with active aryl nucleus.
Organic Compounds Containing Nitrogen mcq solution image
Organic Compounds Containing Nitrogen mcq solution image

Releted MCQ Question on
Organic Chemistry >> Organic Compounds Containing Nitrogen

Releted Question 1

The compound which on reaction with aqueous nitrous acid at low temperature produces an oily nitrosamine is

A. methylamine
B. ethylamine
C. diethylamine
D. triethylamine
Releted Question 2

Acetamide is treated separately with the following reagents. Which one of these would give methylamine?

A. $$PC{l_5}$$
B. $$NaOH + B{r_2}$$
C. soda lime
D. hot conc. $${H_2}S{O_4}$$
Releted Question 3

Carbylamine test is performed in alcoholic \[KOH\]  by heating a mixture of :

A. chloroform and silver powder
B. trihalogenatedmethane and a primary amine
C. an alkyl halide anda primary amine
D. an alkyl cyanide and a primary amine
Releted Question 4

The compound that is most reactive towards electrophilic nitration is :

A. toluene
B. benzene
C. benzoic acid
D. nitrobenzene

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Organic Compounds Containing Nitrogen


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