Solution :
Since the equilateral triangle is inscribed in the circle with centre at the origin, centroid lies on the origin.
So, $$\frac{{AO}}{{OD}} = \frac{2}{1}$$ and $$OD = \frac{1}{2}AO = \frac{a}{2}$$
So, other vertices of triangle have coordinates,
$$\left( { - \frac{a}{2},\,\frac{{\sqrt {3a} }}{2}} \right){\text{ and }}\left[ { - \frac{a}{2},\, - \frac{{\sqrt 3 }}{2}a} \right]$$

$$\therefore $$ Equation of line $$BC$$ is :
$$x = - \frac{a}{2}\, \Rightarrow 2x + a = 0$$