Question

Among the following, the compound that can be most readily sulphonated is

A. benzene
B. nitrobenzene
C. toluene  
D. chlorobenzene
Answer :   toluene
Solution :
TIPS/FORMULAE :
$$ - N{O_2}, - Cl\,\,{\text{and}}\, - OH$$     are electron-attracting or withdrawing group due to $$ - M, - E\,\,\,{\text{and/or}}\, - I$$     effects where as $$C{H_3}$$  show, $$ + I$$  effect ( electron releasing ).
Because of the $$ + I$$  effect of the $$C{H_3}$$  group, toluene has the highest electron density in the  $$o - $$  and $$p - $$ positions and hence can be most readily sulphonated.

Releted MCQ Question on
Organic Chemistry >> General Organic Chemistry

Releted Question 1

The bond order of individual carbon-carbon bonds in benzene is

A. one
B. two
C. between one and two
D. one and two alternately
Releted Question 2

Molecule in which the distance between the two adjacent carbon atoms is largest is

A. Ethane
B. Ethene
C. Ethyne
D. Benzene
Releted Question 3

Among the following, the compound that can be most readily sulphonated is

A. benzene
B. nitrobenzene
C. toluene
D. chlorobenzene
Releted Question 4

The compound 1, 2-butadiene has

A. only $$sp$$   hybridized carbon atoms
B. only $$s{p^2}$$ hybridized carbon atoms
C. both $$sp$$  and $$s{p^2}$$ hybridized carbon atoms
D. $$sp$$ , $$s{p^2}$$ and $$s{p^3}$$ hybridized carbon atoms

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General Organic Chemistry


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