Question
$$AgN{O_3}\left( {aq.} \right)$$ was added to an aqueous $$KCl$$ solution gradually and the conductivity of the solution was measured. The plot of conductance $$\left( \Lambda \right)$$ versus the volume of $$AgN{O_3}\left( {aq.} \right)$$
$$AgN{O_3}\left( {aq.} \right)$$ was added to an aqueous $$KCl$$ solution gradually and the conductivity of the solution was measured. The plot of conductance $$\left( \Lambda \right)$$ versus the volume of $$AgN{O_3}\left( {aq.} \right)$$
A.
$$(P)$$
B.
$$(Q)$$
C.
$$(R)$$
D.
$$(S)$$
Answer :
$$(S)$$
Solution :
$$AgN{O_3}\left( {aq} \right) + KCl\left( {aq} \right) \to AgCl\left( s \right) + KN{O_3}\left( {aq} \right)$$
Conductivity of the solution is almost compensated due to formation of $$KN{O_3}\left( {aq} \right).$$ However, after at end point, conductivity increases more rapidly due to audition of excess $$AgN{O_3}$$ solution.
$$AgN{O_3}\left( {aq} \right) + KCl\left( {aq} \right) \to AgCl\left( s \right) + KN{O_3}\left( {aq} \right)$$
Conductivity of the solution is almost compensated due to formation of $$KN{O_3}\left( {aq} \right).$$ However, after at end point, conductivity increases more rapidly due to audition of excess $$AgN{O_3}$$ solution.