Question

According to molecular orbital theory which of the following statement about the magnetic character and bond order is correct regarding $$O_2^ + $$

A. Paramagnetic and Bond order $$ < {O_2}$$
B. Paramagnetic and Bond order $$ > {O_2}$$  
C. Diamagnetic and Bond order $$ < {O_2}$$
D. Diamagnetic and Bond order $$ > {O_2}$$
Answer :   Paramagnetic and Bond order $$ > {O_2}$$
Solution :
$${O_2}:\sigma 1{s^2},{\sigma ^*}1{s^2},\sigma 2{s^2},{\sigma ^*}2{s^2},\sigma 2p_x^2,$$      $$\left\{ {_{\pi 2p_z^2}^{\pi 2p_y^2},\left\{ {_{{\pi ^*}2p_z^1}^{{\pi ^*}2p_y^1}} \right.} \right.$$
Bond order $$\, = \frac{{10 - 6}}{2} = 2$$
(two unpaired electrons in antibonding molecular orbital)
$$O_2^ + :\,\sigma 1{s^2},{\sigma ^*}1{s^2},\sigma 2{s^2},\sigma 2p_x^2,$$     $$\left\{ {_{\pi 2p_z^2}^{\pi 2p_y^2},\left\{ {_{{\pi ^*}2p_z^0}^{{\pi ^*}2p_y^1}} \right.} \right.$$
Bond order $$ = \frac{{10 - 5}}{2} = 2.5$$
(One unpaired electron in antibonding molecular orbital)
Hence $${O_2}$$ as well as $$O_2^ + $$ is paramagnetic, and bond order of $$O_2^ + $$  is greater than that of $${O_2}.$$

Releted MCQ Question on
Inorganic Chemistry >> Chemical Bonding and Molecular Structure

Releted Question 1

The compound which contains both ionic and covalent bonds is

A. $$C{H_4}$$
B. $${H_2}$$
C. $$KCN$$
D. $$KCl$$
Releted Question 2

The octet rule is not valid for the molecule

A. $$C{O_2}$$
B. $${H_2}O$$
C. $${O_2}$$
D. $$CO$$
Releted Question 3

Element $$X$$ is strongly electropositive and element $$Y$$ is strongly electronegative. Both are univalent. The compound formed would be

A. $${X^ + }{Y^ - }$$
B. $${X^ - }{Y^{ + \,}}$$
C. $$X - Y$$
D. $$X \to Y$$
Releted Question 4

Which of the following compounds are covalent?

A. $${H_2}$$
B. $$CaO$$
C. $$KCl$$
D. $$N{a_2}S$$

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Chemical Bonding and Molecular Structure


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