Question

A substance on treatment with $$dil.{H_2}S{O_4}$$   liberates a colourless gas which produces
(I) turbidity with baryta water and
(II) turns acidified dichromate solution green.
The reaction indicates the presence of

A. $$CO_3^{2 - }$$
B. $${S^{2 - }}$$
C. $$SO_3^{2 - }$$  
D. $$NO_3^ - $$
Answer :   $$SO_3^{2 - }$$
Solution :
\[\begin{align} & N{{a}_{2}}S{{O}_{3}}+2HCl\left( dil \right)\to 2NaCl+{{H}_{2}}O+S{{O}_{2}} \\ & {{K}_{2}}C{{r}_{2}}{{O}_{7}}+{{H}_{2}}S{{O}_{4}}+3S{{O}_{2}}\to {{K}_{2}}S{{O}_{4}}+\underset{\text{Green}}{\mathop{C{{r}_{2}}{{\left( S{{O}_{4}} \right)}_{3}}}}\,+{{H}_{2}}O \\ \end{align}\]

Releted MCQ Question on
Inorganic Chemistry >> Qualitative Analysis

Releted Question 1

The ion that cannot be precipitated by both $$HCl\,{\text{and}}\,{H_2}S$$    is

A. $$P{b^{2 + }}$$
B. $$C{u^ + }$$
C. $$A{g^ + }$$
D. $$S{n^{2 + }}$$
Releted Question 2

Which one among the following pairs of ions cannot be separated by $${H_2}S$$  in dilute hydrochloric acid?

A. $$B{i^{3 + }},S{n^{4 + }}$$
B. $$A{l^{3 + }},H{g^{2 + }}$$
C. $$Z{n^{2 + }},C{u^{2 + }}$$
D. $$N{i^{2 + }},C{u^{2 + }}$$
Releted Question 3

An aqueous solution contains $$H{g^{2 + }},Hg_2^{2 + },P{b^{2 + }}\,{\text{and}}\,C{d^{2 + }}.$$
The addition of $$HCl\left( {6N} \right)$$   will precipitate:

A. $$H{g_2}C{l_2}\,{\text{only}}$$
B. $$PbC{l_2}\,{\text{only}}$$
C. $$PbC{l_2}\,{\text{and}}\,H{g_2}C{l_2}$$
D. $$PbC{l_2}\,{\text{and}}\,HgC{l_2}$$
Releted Question 4

Identify the correct order of solubility of $$N{a_2}S,\,CuS\,{\text{and}}\,ZnS$$     in aqueous medium

A. $$CuS > ZnS > N{a_2}S$$
B. $$ZnS > N{a_2}S > CuS$$
C. $$N{a_2}S > CuS > ZnS$$
D. $$N{a_2}S > ZnS > CuS$$

Practice More Releted MCQ Question on
Qualitative Analysis


Practice More MCQ Question on Chemistry Section