Question

A mono-atomic ideal gas undergoes a process in which the ratio of $$P$$  to $$V$$ at any instant is constant and equals to 1. What is the molar heat capacity of the gas

A. $$\frac{{3R}}{2}$$
B. $${2R}$$  
C. $$0$$
D. $$\frac{{5R}}{2}$$
Answer :   $${2R}$$
Solution :
In general, the molar heat capacity for any process is given by
$$\eqalign{ & C = {C_v} + \frac{R}{{1 - n}},\,{\text{when}}\,P{V^n} = {\text{constant}} \cr & {\text{Here}}\,\,\frac{P}{V} = 1,\,\,\,i.e.\,\,P{V^{ - 1}} = {\text{constant}} \cr & {\text{For}}\,{\text{monoatomic}}\,{\text{gas,}}\,\,{C_v} = \frac{3}{2}R \cr & \therefore \,\,C = \frac{3}{2}R + \frac{R}{{1 - \left( { - 1} \right)}} = \frac{3}{2}R + \frac{R}{2} = \frac{{4R}}{2} = 2R. \cr} $$

Releted MCQ Question on
Physical Chemistry >> States of Matter Solid, Liquid and Gas

Releted Question 1

Equal weights of methane and oxygen are mixed in an empty container at $${25^ \circ }C.$$  The fraction of the total pressure exerted by oxygen is

A. $$\frac{1}{3}$$
B. $$\frac{1}{2}$$
C. $$\frac{2}{3}$$
D. $$\frac{1}{3} \times \frac{{273}}{{298}}$$
Releted Question 2

The temperature at which a real gas obeys the ideal gas laws over a wide range of pressure is

A. Critical temperature
B. Boyle temperature
C. Inversion temperature
D. Reduced temperature
Releted Question 3

The ratio of root mean square velocity to average velocity of a gas molecule at a particular temperature is

A. 1.086 : 1
B. 1 : 1.086
C. 2 : 1.086
D. 1.086 : 2
Releted Question 4

Helium atom is two times heavier than a hydrogen molecule. At $$298 K,$$  the average kinetic energy of a helium atom is

A. two times that of a hydrogen molecule.
B. same as that of a hydrogen molecule.
C. four times that of a hydrogen molecule.
D. half that of a hydrogen molecule.

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States of Matter Solid, Liquid and Gas


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