Energy levels of $$H$$-atom are given by
$$\eqalign{
& {E_n} = - \frac{{13.6{Z^2}}}{{{n^2}}}eV\,\,\left( {Z = 1} \right) \cr
& \Rightarrow {E_n} = \frac{{ - 13.6}}{{{n^2}}}\,eV \cr} $$
Photons are emitted only when electron jumps from higher energy level (higher $$n$$-value) to lower energy level (lower $$n$$-value). So, alternative (a) and (c) are wrong.
Energy difference from $$n = 2$$ to $$n = 1$$ level is
$$\Delta {E_{2 \to 1}} = 13.6\left( {\frac{1}{{{1^2}}} - \frac{1}{{{2^2}}}} \right)eV = 13.6 \times \frac{3}{4} = 10.2\,eV$$
$$\eqalign{
& \Delta {E_{6 \to 2}} = 13.6\left( {\frac{1}{{{2^2}}} - \frac{1}{{{6^2}}}} \right) \cr
& = 13.6 \times \left( {\frac{1}{4} - \frac{1}{{36}}} \right) = 13.6 \times \frac{2}{9} = 3.02\,eV \cr} $$
Thus, it is evident that difference is larger for $$n = 2$$ to $$n = 1$$ transition. Hence, maximum energy photon or shortest wavelength will be emitted during transition from $$n =2$$ to $$n = 1$$
42.
If the atom $$_{100}F{m^{257}}$$ follows the Bohr model and the radius of $$_{100}F{m^{257}}$$ is $$n$$ times the Bohr radius, then find $$n.$$
KEY CONCEPT : For an atom following Bohr’s model, the radius is given by
$${r_m} = \frac{{{r_0}{m^2}}}{Z}$$ where $${r_0}$$ = Bohr’s radius and $$m$$ = orbit number.
For $$Fm,m = 5$$ (Fifth orbit in which the outermost electron is present)
$$\therefore {r_m} = \frac{{{r_0}{5^2}}}{{100}} = n{r_0}\left( {{\text{given}}} \right) \Rightarrow n = \frac{1}{4}$$
43.
If the series limit frequency of the Lyman series is $${\nu _1},$$ then the series limit frequency of the $$P$$-fund series is :
The energy of hydrogen like atom in its $$n$$th excited state is given by
$${E_n} = - 13.6\frac{{{Z^2}}}{{{n^2}}}.$$
For ground state $$\left( {n = 1} \right),$$ and atomic number $$\left( Z \right) = 1$$
$${E_1} = - \frac{{13.6}}{{{{\left( 1 \right)}^2}}} = - 13.6\,eV$$
For first excited state $$\left( {n = 2} \right),$$
$$\eqalign{
& {E_2} = - \frac{{13.6}}{{{{\left( 2 \right)}^2}}} = - \frac{{13.6}}{4} \cr
& = - 3.4\,eV \cr} $$ NOTE
In ground state $$\left( {n = 1} \right)$$ energy of atom is $$-13.6\,eV$$ and energy corresponding to $$n = \infty $$ is zero. Therefore, energy required to remove the electron from ground state is $$13.6\,eV.$$
45.
The ground state energy of hydrogen atom is $$-13.6\,eV.$$ When its electron is in the first excited state, its excitation energy is
Electron after absorbing $$10.2\,eV$$ energy goes to its first excited state $$\left( {n = 2} \right)$$ from ground state $$\left( {n = 1} \right).$$
$$\therefore $$ Increase in momentum $$ = \frac{h}{{2\pi }}$$
$$ = \frac{{6.6 \times {{10}^{ - 34}}}}{{6.28}} = 1.05 \times {10^{ - 34}}J - s.$$
47.
An energy of $$24.6\,eV$$ is required to remove one of the electrons from a neutral helium atom. The energy (in $$eV$$ ) required to remove both the electrons from a neutral helium atom is
49.
If the electron revolving around the nucleus in a radius $$'r'$$ with orbital speed $$'v'$$ has magnetic moment $$\frac{{evr}}{2}.$$ Hence, using Bohr's postulate of the quantization of angular momentum obtain the magnetic moment $$\left( M \right)$$ of hydrogen atom in its ground state and current $$\left( I \right)$$ due to revolution of electron.
A
$$M = \frac{{eh}}{{4\pi m}},I = \frac{{eV}}{{2\pi r}}$$
B
$$M = \frac{{2eh}}{{5\pi m}},I = \frac{{eV}}{{4\pi r}}$$
C
$$M = \frac{h}{{\pi m}},I = \frac{e}{{\pi r}}$$
D
$$M = \frac{{eh}}{{\pi m}},I = \frac{{eV}}{{\pi r}}$$
$$\eqalign{
& I = \frac{e}{T} = \frac{{eV}}{{2\pi r}} \cr
& {\text{so,}}\,M = \frac{{eV}}{{2\pi r}} \times \pi {r^2} = \frac{{evr}}{2} \cr} $$
According to Bohr’s theory angular momentum
$$\eqalign{
& mvr = \frac{{nh}}{{2\pi }}\,\,{\text{or}}\,\,vr = \frac{{nh}}{{2\pi m}} \cr
& {\text{so,}}\,\,M = \frac{{neh}}{{4\pi m}} \cr} $$
For the ground state $$n = 1\,{\text{so,}}\,\,M = \frac{{eh}}{{4\pi m}}$$
50.
Suppose that a material emits X-rays of wavelengths $${\lambda _{{K_\alpha }}},{\lambda _{{K_\beta }}},{\lambda _{{L_\alpha }}},$$ when it is excited by fast moving electrons; the wavelengths corresponding to $${K_\alpha },{K_\beta },{L_\alpha }$$ X- rays of the material respectively. Then we can write
The energy level diagram of the atom is shown in the figure. It is clear that
$$\eqalign{
& {E_{{K_\beta }}} = {E_{{K_\alpha }}} + {E_{{L_\alpha }}} \cr
& {\text{or,}}\,\,{v_{{K_\beta }}} = {v_{{K_\alpha }}} + {v_{{L_\alpha }}} \cr
& {\text{or,}}\,\,\frac{1}{{{\lambda _{{K_\beta }}}}} = \frac{1}{{{\lambda _{{K_\alpha }}}}} + \frac{1}{{{\lambda _{{L_\alpha }}}}} \cr} $$